Substances and mixtures, which in contact with water, emit flammable gases, Category 1
Acute toxicity - Category 4, Oral
Skin corrosion, Sub-category 1B
Acute toxicity - Category 4, Inhalation
Specific target organ toxicity – repeated exposure, Category 1
H260 In contact with water releases flammable gases which may ignite spontaneously
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H332 Harmful if inhaled
H372 Causes damage to organs through prolonged or repeated exposure
P223 Do not allow contact with water.
P231+P232 Handle and store contents under inert gas/....Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P302+P335+P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].
P370+P378 In case of fire: Use ... to extinguish.
P301+P317 IF SWALLOWED: Get medical help.
P330 Rinse mouth.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316 Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P317 Get medical help.
P319 Get medical help if you feel unwell.
P402+P404 Store in a dry place. Store in a closed container.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Rinse with pure water for at least 15 minutes. Consult a doctor.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
This material is highly toxic by inhalation. (EPA, 1998)
If strong concentrations of boron trifluoride gas get into the eyes, wash eyes immediately with large amounts of water, lifting the lower and upper lids occasionally. Get medical attention immediately. Contact lenses should not be worn when working with this chemical. Boron trifluoride
If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped. Do not use water. Use graphite, soda ash, powdered sodium chloride, or suitable dry powder.
Fire may produce irritating or poisonous gases. Flammable/combustible material which may be ignited by heat spark or flame. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewer. Runoff to sewer may create fire or explosion hazard. When heated to decomposition, it emits toxic fumes of fluorides. (EPA, 1998)
Wear self-contained breathing apparatus for firefighting if necessary.
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Environmental considerations: land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial sorbents.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.
Component | Dimethyl ether--boron trifluoride |
---|---|
CAS No. | 353-42-4 |
Recommended Exposure Limit: Ceiling Value: 1 ppm (3 mg/cu m). /Boron trifluoride/ |
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
no data available
Boron trifluoride dimethyl etherate is a fuming liquid. Corrosive to skin, eyes and mucous membranes. May be toxic by inhalation. Used as a catalyst in chemical reactions.
Liquid
no data available
-14°C
126-127°C
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62°C
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no data available
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no data available
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1.239
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no data available
25 ppm Boron trifluoride
no data available
Moderate fire risk. CombustibleBORON TRIFLUORIDE DIMETHYL ETHERATE is a flammable, corrosive, and toxic liquid, moisture-sensitive. Emits toxic fluoride fumes when heated to decomposition [Lewis, 3rd ed., 1993, p. 189].
no data available
Interaction of ... /hexafluorisopropylideneaminolithium/ with a range of chloro- and fluoro-derivatives of boron ... during warming to 25 deg C tended to be violently exothermic in absence of solvent.
When heated to decomposition it emits toxic fumes of /hydrogen fluoride/.
no data available
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A4; Not classifiable as a human carcinogen. Fluorides, as F
no data available
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN2965 (For reference only, please check.)
IMDG: UN2965 (For reference only, please check.)
IATA: UN2965 (For reference only, please check.)
ADR/RID: BORON TRIFLUORIDE DIMETHYL ETHERATE (For reference only, please check.)
IMDG: BORON TRIFLUORIDE DIMETHYL ETHERATE (For reference only, please check.)
IATA: BORON TRIFLUORIDE DIMETHYL ETHERATE (For reference only, please check.)
ADR/RID: 4.3 (For reference only, please check.)
IMDG: 4.3 (For reference only, please check.)
IATA: 4.3 (For reference only, please check.)
ADR/RID: I (For reference only, please check.)
IMDG: I (For reference only, please check.)
IATA: I (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
no data available