Acute toxicity - Category 4, Oral
H302 Harmful if swallowed
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301+P317 IF SWALLOWED: Get medical help.
P330 Rinse mouth.
none
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest.
Rinse skin with plenty of water or shower.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth.
Inhalation causes irritation of nose and throat. Ingestion causes gastrointestinal disturbances. Dust irritates eyes. (USCG, 1999)
Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for signs of pulmonary edema and treat if necessary . Monitor for shock and treat if necessary . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport . Do not use emetics. For ingestion, rinse mouth and administer 5 mg/kg up to 200 mL of water for dilution if the patent can swallow, has a strong gag reflex, and does not drool . Do not attempt to neutralize. Ammonia and related compounds
During fire fighting/ wear goggles and self-contained breathing apparatus.
Special Hazards of Combustion Products: Toxic oxides of nitrogen may form in fires. (USCG, 1999)
In case of fire in the surroundings, use appropriate extinguishing media.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Then wash away with plenty of water.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Then wash away with plenty of water.
Environmental considerations - Land spill: Dig a pit, pond, lagoon, or holding area to contain liquid or solid material. /SRP: If time permits, pits, ponds, lagoons, soak holes, or holding areas should be sealed with an impermeable flexible membrane liner./ Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Dry. Well closed. Separated from strong oxidants and acids.Storage temp: ambient
TLV: 10 mg/m3, as TWA
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles.
Protective gloves.
Use local exhaust or breathing protection.
no data available
Ammonium sulfamate is a white crystalline solid. It is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is used to flameproof fabrics and papers, in weed or brush killing products, and for other uses.
Hygroscopic crystals (large plates)
Odorless
-26°C(lit.)
218°C
Noncombustible Solid
no data available
99°C(lit.)
no data available
160°C
pH of 0.27M soln in water = 4.9
no data available
200 % (NIOSH, 2016)
no data available
0 mm Hg (approx) (NIOSH, 2016)
1.8 g/cm3
no data available
no data available
Decomposes above 160°C . This produces ammonia, nitrogen oxides and sulfur oxides. The solution in water is a weak acid. Attacks mild steel. Contact with hot water may cause formation of large amounts of steam. Reacts with acids and strong oxidants.
Hydrolysed at higher temperatures and in acidic conditions.
Not flammableAMMONIUM SULFAMATE is incompatible with the following: Acids, hot water [Note: Elevated temperatures cause a highly exothermic reaction with water.] (NIOSH, 2016).
no data available
In hot acid solution this material can undergo spontaneous hydrolysis, liberating much heat.
Toxic gases and vapors (such as ... carbon monoxide) may be released when ammonium sulfamate decomposes.
no data available
no data available
no data available
no data available
no data available
no data available
The substance is irritating to the eyes.
no data available
A harmful concentration of airborne particles can be reached quickly on spraying or when dispersed, especially if powdered.
Strains of aureobasidum (pullularia) pullulans, aphalosporium acremonium, & 2 unidentified species of achromobacter & flavobacterium used sulfamic acid (sodium salt) as source of nitrogen. both fungi & bacteria converted sulfamate to sulfate in approx equimolar prop to amt of nitrogen assimilated.
Food chain concn potential: none
From its lack of response to soil type and its behavior in field plots ... /it was/ concluded that /ammonium sulfamate/ is not retained in soil, but moves with soil moisture like chlorate.
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available