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Fresh air, rest. Refer for medical attention.
Remove contaminated clothes. Rinse and then wash skin with water and soap. Seek medical attention if you feel unwell.
Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer for medical attention.
Rinse mouth. Refer immediately for medical attention.
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Use dry chemical, carbon dioxide or alcohol-resistant foam.
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
In case of fire in the surroundings, use appropriate extinguishing media.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Vacuum with specialist equipment (See Notes) or carefully sweep into containers. Carefully collect remainder. Then store and dispose of according to local regulations.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Provision to contain effluent from fire extinguishing. Separated from acids, strong oxidants, bases and food and feedstuffs. Well closed. Dry. Do NOT store or transport in containers made from metal. Store in an area without drain or sewer access.
TLV: 0.01 mg/m3, as TWA; A1 (confirmed human carcinogen); BEI issued.MAK: skin absorption (H); carcinogen category: 1; germ cell mutagen group: 3A
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear face shield or eye protection in combination with breathing protection if powder.
Protective gloves. Protective clothing.
Use closed system, ventilation or breathing protection.
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white to off-white powder
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Solubility in water: good
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1.989
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No data.Decomposes on heating. This produces toxic and corrosive fumes. Reacts with acids. This produces toxic arsine gas (see ICSC 0222). Attacks many metals such as iron, aluminium and zinc in the presence of water. This produces toxic fumes of arsenic (see ICSC 0013) and arsine (see ICSC 0222). Reacts with strong oxidants and bases. This produces toxic and corrosive fumes including ammonia.
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The substance is irritating to the eyes and respiratory tract. Ingestion could cause effects on the gastrointestinal tract. This may result in severe gastroenteritis, loss of fluids and electrolytes, cardiac disorders and shock. Exposure far above the OEL could cause death. The effects may be delayed. Medical observation is indicated.
The substance may have effects on the skin, mucous membranes, peripheral nervous system, bone marrow and liver. This may result in pigmentation disorders, hyperkeratosis, perforation of the nasal septum, neuropathy, anaemia and liver impairment. This substance is carcinogenic to humans. Animal tests show that this substance possibly causes toxicity to human reproduction or development.
A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1546 (For reference only, please check.)
IMDG: UN1546 (For reference only, please check.)
IATA: UN1546 (For reference only, please check.)
ADR/RID: AMMONIUM ARSENATE (For reference only, please check.)
IMDG: AMMONIUM ARSENATE (For reference only, please check.)
IATA: AMMONIUM ARSENATE (For reference only, please check.)
ADR/RID: 6.1 (For reference only, please check.)
IMDG: 6.1 (For reference only, please check.)
IATA: 6.1 (For reference only, please check.)
ADR/RID: II (For reference only, please check.)
IMDG: II (For reference only, please check.)
IATA: II (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
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NEVER use a domestic-type vacuum cleaner to vacuum the substance, only use specialist equipment.Depending on the degree of exposure, periodic medical examination is suggested.Do NOT take working clothes home.