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Fresh air, rest.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer for medical attention.
Rinse mouth. Give one or two glasses of water to drink.
An allergen. Irritating to eyes, skin and mucous membranes. Toxic via inhalation, ingestion and percutaneous absorption. Repeated low grade exposures may cause headache, pruritis, skin eruptions, yellowing of skin and conjunctiva, vomiting, diarrhea, and oliguria. Severe human poisonings, resulting from ingestion of one or two grams of material, may be characterized by gastroenteritis, hemorrhagic nephritis with anuria, acute hepatitis, progressive stupor, coma, and death. (USCG, 1999)
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]: Fire may produce irritating, corrosive and/or toxic gases. (ERG, 2016)
Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Inorganic acids and related compounds
Use extreme care as ammonium picrate will explode when heated or shocked, especially when dry. This chemical is a flammable solid. Use flooding quantities of water, applied from a distance ... If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters. Notify local health and fire officials and pollution control agencies. From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure position ... The only respirators recommended for fire fighting are self-contained breathing apparatuses that have full facepieces and are operated in a pressure-demand or other positive-pressure mode.
Special Hazards of Combustion Products: Contain highly toxic NOx fumes. Behavior in Fire: Flammable solid. UNCONFINED material burns without detonation when ignited. Confined material will explode upon heating to its ignition temperature. (USCG, 1999)
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]: MAY EXPLODE AND THROW FRAGMENTS 1600 METERS (1 MILE) OR MORE IF FIRE REACHES CARGO. For information on "Compatibility Group" letters, refer to Glossary section. (ERG, 2016)
Use water in large amounts, water spray, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.
Consult an expert! Evacuate danger area! Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment.
Consult an expert! Evacuate danger area! Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment.
Consult an expert! Evacuate danger area! Personal protection: particulate filter adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment.
NO open flames. Do NOT expose to friction or shock. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Separated from incompatible materials. See Chemical Dangers. Store in an area without drain or sewer access.Incompatible with strong oxidizers, strong bases. Contact with air causes substance to give off corrosive anhydrous ammonia fumes. Outside, detached storage is recommended. Store to avoid heat, shock, or the presence of reducing materials. Use only non-sparking tools and equipment, especially when opening and closing containers of this chemical. Sources of ignition, such as smoking and open flames, are prohibited where this chemical is used, handled, or stored in a matter that could create a potential fire or explosion hazard.
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles.
Protective gloves.
Use ventilation (not if powder), local exhaust or breathing protection.
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Ammonium picrate, wetted with not less than 10% water is a slurry or sludge of yellow crystals in water. Will burn, although may be difficult to ignite. Produces toxic oxides of nitrogen during combustion.
Bright yellow scales or orthorhombic crystals; "red modification" is not a distinct polymorph, but a slightly contaminated form of the yellow salt.
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280(分解)°C
303.6°C at 760mmHg
Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Many reactions may cause fire or explosion. See Notes.
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133.9°C
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265°C
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Slightly soluble in alcohol
-1.4
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1.856g/cm3
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May decompose on shock, friction or concussion. May explode on heating. On combustion, forms toxic gases including nitrogen oxides. Reacts with metals and reducing agents. This generates fire and explosion hazard. Reacts with concrete and plaster. This produces salts of picric acid, more sensitive to shock than ammonium picrate.
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Moderately flammable by spontaneous chemical reaction.AMMONIUM PICRATE is a high explosive when dry [Hawley]. Mixing with water greatly reduces its sensitivity to shock, friction and heat. Traces of metallic picrates may significantly lower the temperature at which this mixture will explode (Military Explosives p. 96).
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A powerful oxidizer that reacts violently with reducing agents ... Keep away from metals, sodium nitrite, perchlorates, peroxides, permanganates, and any form of shock.
When heated to decomposition it emits highly toxic fumes of /nitroxides/.
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The substance is irritating to the skin and eyes. The substance may cause effects on the blood. This may result in destruction of blood cells and acidosis.
Repeated or prolonged contact with skin may cause dermatitis.
A harmful concentration of airborne particles can be reached quickly when dispersed.
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN0004 (For reference only, please check.)
IMDG: UN0004 (For reference only, please check.)
IATA: UN0004 (For reference only, please check.)
ADR/RID: AMMONIUM PICRATE dry or wetted with less than 10% water, by mass? (For reference only, please check.)
IMDG: AMMONIUM PICRATE dry or wetted with less than 10% water, by mass? (For reference only, please check.)
IATA: AMMONIUM PICRATE dry or wetted with less than 10% water, by mass? (For reference only, please check.)
ADR/RID: 1.1D (For reference only, please check.)
IMDG: 1.1D (For reference only, please check.)
IATA: 1.1D (For reference only, please check.)
ADR/RID: (For reference only, please check.)
IMDG: (For reference only, please check.)
IATA: (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
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For safety transportation, 10-20% water is usually added.In normal conditions: combustible; if oxidized may become explosive.Other UN number is 1310, with not less than 10% water by mass, hazard class 4.1, packing group I.