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Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Rinse with pure water for at least 15 minutes. Consult a doctor.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Excerpt from ERG Guide 150 [Substances (Self-Reactive / Temperature Controlled)]: Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death. May produce irritating, toxic and/or corrosive gases. Runoff from fire control may cause pollution. (ERG, 2016)
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Excerpt from ERG Guide 150 [Substances (Self-Reactive / Temperature Controlled)]: The temperature of the substance must be maintained at or below the "Control Temperature" at all times. SMALL FIRE: Dry chemical, CO2, water spray or regular foam. LARGE FIRE: Flood fire area with water from a distance. Move containers from fire area if you can do it without risk. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: BEWARE OF POSSIBLE CONTAINER EXPLOSION. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)
Excerpt from ERG Guide 150 [Substances (Self-Reactive / Temperature Controlled)]: Self-decomposition, self-polymerization, or self-ignition may be triggered by heat, chemical reaction, friction or impact. Self-accelerating decomposition may occur if the specific control temperature is not maintained. These materials are particularly sensitive to temperature rises. Above a given "Control Temperature" they decompose or polymerize violently and may catch fire. May be ignited by heat, sparks or flames. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Some may decompose explosively when heated or involved in a fire. May burn violently. Decomposition or polymerization may be self-accelerating and produce large amounts of gases. Vapors or dust may form explosive mixtures with air. (ERG, 2016)
Wear self-contained breathing apparatus for firefighting if necessary.
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
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2,5-diethoxy-4-morpholinobenzenediazonium zinc chloride is a white to light-colored solid. Insoluble in water and denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.
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Dust may form an explosive mixture in air. Insoluble in water.
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Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. Self-accelerating decomposition may occur if the specific control temperature is not maintained. 2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM ZINC CHLORIDE is a diazonium salt, a class of compounds which can be shock-sensitive and decompose violently with heating. Because they are so unstable, they are usually not isolated, but are instead used as intermediates for organic syntheses. Many diazonium salts are susceptible to displacement reactions by various substrates, generating nitrogen gas (N2) as a by-product. Another common reaction pathway is to undergo a coupling reaction to form a diazo compound. Diazonium salts in general are high energy materials that can decompose violently either by heating or by mechanical force (shock-sensitive), so in that sense, they may be considered self-reactive. Stability often is improved by adding zinc chloride or other salts. Conversely, exposure to bases, transition metal impurities (e.g. Cu, Sn), nitrous acid and/or direct sunlight can promote decomposition and lower the onset temperature of decomposition. Diazonium salts should never be heated above 40°C and the dried powder should not be "scratched" with a metal spatula or ground finely, as this friction could be enough to cause an explosive decomposition (H. Zollinger, Diazotization of amines and dediazoniation of diazonium ions. In S. Patai, The Chemistry of Amino, Nitroso, Nitro and Related Groups, John Wiley & Sons, Ltd. (1996), 627).
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
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