Skin irritation, Category 2
Serious eye damage, Category 1
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1
H315 Causes skin irritation
H318 Causes serious eye damage
H410 Very toxic to aquatic life with long lasting effects
P264 Wash ... thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P273 Avoid release to the environment.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P321 Specific treatment (see ... on this label).
P332+P317 If skin irritation occurs: Get medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P317 Get medical help.
P391 Collect spillage.
none
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Rinse with pure water for at least 15 minutes. Consult a doctor.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
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Use dry chemical, carbon dioxide or alcohol-resistant foam.
no data available
Wear self-contained breathing apparatus for firefighting if necessary.
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.
Component | 4-(1,1,3,3-tetramethylbutyl)phenol | |||
---|---|---|---|---|
CAS No. | 140-66-9 | |||
Limit value - Eight hours | Limit value - Short term | |||
ppm | mg/m3 | ppm | mg/m3 | |
Germany (DFG) | 0,5 (1) | 4,3 (1) | 0,5 (1)(2) | 4,3 (1)(2) |
Switzerland | 0,5 | 4,3 | 0,5 (1) | 4,3 (1) |
Remarks | ||||
Germany (DFG) | (1) Inhalable fraction and vapour (2) 15 minutes average value | |||
Switzerland | (1) 15 minutes average value |
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
no data available
Solid. Flakes.
White.
no data available
85 °C. Atm. press.:Ca. 1 atm.
289 °C. Atm. press.:Ca. 101 kPa.
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85°C(lit.)
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In water: 7 mg/L. Temperature:20 °C. pH:> 6 - < 7.
log Pow = 4.8. Temperature:22 °C.
0.02 mBar. Temperature:38 °C.
0.37 g/cm3. Temperature:22 °C.
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When heated to decomp it emits acrid smoke and fumes.
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In experiments with a soil column, concentrations of 4-(1,1,3,3-tetramethylbutyl)phenol were about two orders of magnitude lower in the column effluent than in the feed(1). Soil from this column, which had undergone 3 inundation cycles with 4-(1,1,3,3-tetramethylbutyl)phenol at 10 ug/l, required 16 hours to convert 7% of this compound to CO2. Microbial adaptation was noted for this compound, as indicated by increased removal efficiencies during successive inundation cycles (6 day flooding, 16 day drying cycle) at varying concentrations. Column effluent concentrations of 4-(1,1,3,3-tetramethylbutyl)phenol were independent of input concentrations during the final stage of the test(1). Following three aerobic flooding cycles, anaerobic conditions were introduced(2). Fractional breakthrough profiles for 4-(1,1,3,3-tetramethylbutyl)phenol did not change (from those obtained during aerobic test conditions) although the degree of breakthrough increased for this compound; this indicates that the inhibition in compound removal mediated by anaerobic conditions is not due solely to cessation of mineralization activity(2).
An estimated BCF value of 6000 was calculated for 4-(1,1,3,3-tetramethylbutyl)phenol(SRC), using an estimated log Kow of 5.28(1,SRC) and a recommended regression-derived equation(2). According to a recommended classification scheme(3), this BCF value suggests that bioconcentration in aquatic organisms will be an important fate process(SRC).
The Koc of 4-(1,1,3,3-tetramethylbutyl)phenol is estimated as approximately 18,000(SRC), using an estimated log Kow of 5.28(1,SRC) and a regression-derived equation(2,SRC). According to a recommended classification scheme(3), this estimated Koc value suggests that 4-(1,1,3,3-tetramethylbutyl)phenol will be immobile in soil(SRC). However, this compound was measured in wells down gradient from the flooding basins (0.17 ug/L) during rapid infiltration of primary sewage (containing 4-(1,1,3,3-tetramethylbutyl)phenol at 0.79 ug/L) at a kame site(4). Sorption processes did not appear to completely control the movement of this compound through soil(4). This compound was again present in wells down gradient from the initial site(at 0.01-0.017 ug/L) at another rapid infiltration site in Arizona (4-(1,1,3,3-tetramethylbutyl)phenol initially present at 0.757 ug/L); here, removal of 4-(1,1,3,3-tetramethylbutyl)phenol was attributed mainly to sorption processes as the sewage had been through secondary treatment(5).
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available