Acute toxicity - Category 4, Oral
Skin irritation, Category 2
Specific target organ toxicity – single exposure, Category 3
H302 Harmful if swallowed
H315 Causes skin irritation
H336 May cause drowsiness or dizziness
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P301+P317 IF SWALLOWED: Get medical help.
P330 Rinse mouth.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P321 Specific treatment (see ... on this label).
P332+P317 If skin irritation occurs: Get medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P319 Get medical help if you feel unwell.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest. Refer for medical attention.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Refer for medical attention .
no data available
no data available
Use AFFF, alcohol-resistant foam, dry powder, carbon dioxide.
Combustible. Above 70°C explosive vapour/air mixtures may be formed.
Use AFFF, alcohol-resistant foam, dry powder, carbon dioxide.
Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO open flames. Above 70°C use a closed system and ventilation. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Ventilation along the floor.
Component | 4-methylcyclohexanol, mixed isomers | |||
---|---|---|---|---|
CAS No. | 589-91-3 | |||
Limit value - Eight hours | Limit value - Short term | |||
ppm | mg/m3 | ppm | mg/m3 | |
Canada - Ontario | 50 | ? | ? | ? |
Denmark | 50 | 235 | 100 | 470 |
Ireland | 50 | 235 | 75 (1) | 350 (1) |
Remarks | ||||
Ireland | (1) 15 minutes reference period |
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety spectacles.
Protective gloves.
Use ventilation.
no data available
COLOURLESS LIQUID.
no data available
no data available
312°C(dec.)(lit.)
120°C/16mmHg(lit.)
Combustible.
no data available
68°C
295°C
no data available
no data available
no data available
in water: poor
1.79
1.5 mm Hg ( 30 °C)
0.914
3.94 (vs air)
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
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no data available
The substance is mildly irritating to the eyes and skin. The vapour at high levels is irritating to the eyes and upper respiratory tract.
Repeated or prolonged contact with skin may cause dermatitis.
A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C.
no data available
no data available
no data available
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1987 (For reference only, please check.)
IMDG: UN1987 (For reference only, please check.)
IATA: UN1987 (For reference only, please check.)
ADR/RID: ALCOHOLS, N.O.S. (For reference only, please check.)
IMDG: ALCOHOLS, N.O.S. (For reference only, please check.)
IATA: ALCOHOLS, N.O.S. (For reference only, please check.)
ADR/RID: 3 (For reference only, please check.)
IMDG: 3 (For reference only, please check.)
IATA: 3 (For reference only, please check.)
ADR/RID: II (For reference only, please check.)
IMDG: II (For reference only, please check.)
IATA: II (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
no data available
This substance exists in two geometrical isomers (cis and trans).Other boiling points: 173°C (cis), 174°C (trans).Melting point: -9.2°C (cis).