Acute toxicity - Category 3, Oral
Acute toxicity - Category 4, Dermal
Skin sensitization, Category 1
Acute toxicity - Category 3, Inhalation
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1
H301 Toxic if swallowed
H312 Harmful in contact with skin
H317 May cause an allergic skin reaction
H331 Toxic if inhaled
H410 Very toxic to aquatic life with long lasting effects
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P301+P316 IF SWALLOWED: Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P330 Rinse mouth.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P317 Get medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P333+P317 If skin irritation or rash occurs: Get medical help.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316 Get emergency medical help immediately.
P391 Collect spillage.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest.
Rinse and then wash skin with water and soap.
Rinse with plenty of water (remove contact lenses if easily possible).
Rinse mouth.
SYMPTOMS: Symptoms of exposure to this compound include eye, skin, and mucous membrane irritation; headache; drowsiness; and unsteadiness. Chronic symptoms include liver damage. ACUTE/CHRONIC HAZARDS: This compound emits highly toxic fumes when heated to decomposition. (NTP, 1992)
Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary . Monitor for shock and treat if necessary . Anticipate seizures and treat if necessary . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal . Aromatic hydrocarbons and related compounds
Fires involving this compound can be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
This chemical is combustible. (NTP, 1992)
Use powder, water spray, foam, carbon dioxide.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Do NOT let this chemical enter the environment.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Do NOT let this chemical enter the environment.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO open flames. Prevent deposition of dust. Closed system, dust explosion-proof electrical equipment and lighting. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Separated from strong oxidants, strong bases and food and feedstuffs. Provision to contain effluent from fire extinguishing.
MAK: skin absorption (H); carcinogen category: 3B
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety spectacles.
Protective gloves.
Use ventilation (not if powder).
no data available
Solid. Solified melt.
Yellow.
no data available
43 °C.
255.5 °C. Atm. press.:1 013 hPa.
Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
no data available
124 °C. Atm. press.:1 013 hPa.
420 °C. Atm. press.:1 013 hPa.
no data available
5.8. Remarks:Saturated solution.
dynamic viscosity (in mPa s) = 2.87. Temperature:60.0°C.;dynamic viscosity (in mPa s) = 2.37. Temperature:70.0°C.;dynamic viscosity (in mPa s) = 1.52. Temperature:100.0°C.
less than 0.1 mg/mL at 74.3° F (NTP, 1992)
log Pow = 3.04.
0.02 hPa. Temperature:25 °C. Remarks:Calculated on the basis of an experimentally determined equation.
1.46. Temperature:75 °C.
6.63 (NTP, 1992) (Relative to Air)
no data available
Decomposes on heating and on burning. This produces toxic fumes of nitrogen oxides and hydrogen chloride (see ICSC 0163). Reacts violently with oxidants and strong bases.
no data available
Fire risk by spontaneous reaction.Can react vigorously with oxidizing materials. (NTP, 1992)
no data available
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No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.
AEROBIC: Under conditions of industrial waste treatment plants, microbial sludge populations are capable of reducing influent 3,4-dichloronitrobenzene to 3,4-dichloroaniline(1). No aerobic biodegradation was observed for initial concns of 0.5X10-6 to 50X10-6 g/L of 3,4-dichloronitrobenzene innoculated in an aquifer slurry over an unspecified time frame(2).
Experimental BCF values of 104-130 (mean BCF of 120) following exposure of 5 to 36 days to 720 ng/L test compound(2) were obtained from freshwater rainbow trout, Salmo gairdneri(1,2). According to a classification scheme(3), these BCF values suggest that bioconcentration in aquatic organisms is high(SRC).
An experimentally determined mean Koc value of 393 for 3,4-dichloronitrobenzene was reported using 4 silt loam soils(1). A log Koc value of 2.62 was reported following adsorption studies using sediment from the Yangste River in China(2), corresponding to a Koc of 390(SRC). According to a classification scheme(3), these Koc values suggest that 3,4-dichloronitrobenzene is expected to have moderate mobility in soil. Using a modified organo montmorillonite clay from Jiangning Jinagsu Province, China, a log Koc of 3.76 was determined(3), corresponding to a Koc of 5,754(SRC).
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN2811 (For reference only, please check.)
IMDG: UN2811 (For reference only, please check.)
IATA: UN2811 (For reference only, please check.)
ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. (For reference only, please check.)
IMDG: TOXIC SOLID, ORGANIC, N.O.S. (For reference only, please check.)
IATA: TOXIC SOLID, ORGANIC, N.O.S. (For reference only, please check.)
ADR/RID: 6.1 (For reference only, please check.)
IMDG: 6.1 (For reference only, please check.)
IATA: 6.1 (For reference only, please check.)
ADR/RID: I (For reference only, please check.)
IMDG: I (For reference only, please check.)
IATA: I (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available
Health effects of exposure to the substance have not been investigated adequately.