Skin irritation, Category 2
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1
H315 Causes skin irritation
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
P264 Wash ... thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P273 Avoid release to the environment.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P321 Specific treatment (see ... on this label).
P332+P317 If skin irritation occurs: Get medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
none
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .
Irritates eyes and (on prolonged contact) skin. Ingestion causes irritation of mouth and stomach. (USCG, 1999)
no data available
Fire Extinguishing Agents Not to Be Used: Water may be ineffective. Fire Extinguishing Agents: Dry chemical, foam, carbon dioxide (USCG, 1999)
Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. (ERG, 2016)
Use water spray, foam, powder, carbon dioxide.
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered plastic containers. Carefully collect remainder. Then store and dispose of according to local regulations.
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered plastic containers. Carefully collect remainder. Then store and dispose of according to local regulations.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Store in an area without drain or sewer access. Separated from food and feedstuffs. See Chemical Dangers.
no data available
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles.
Protective gloves.
Use local exhaust or breathing protection.
no data available
Solid.
Light straw, crystalline solid
no data available
37 °C.
253 °C. Atm. press.:Ca. 1 atm.
Combustible.
no data available
Ca. 108.5 °C. Atm. press.:Ca. 101.3 kPa.
375°C
no data available
no data available
no data available
2.5 mg/l @ 25 deg C
log Pow = 4.5. Temperature:24 °C. Remarks:PH not reported.
0.008 mm Hg. Temperature:20 °C. Remarks:Standard Deviation of 0.0003 mm Hg.
0.914 g/cm3. Temperature:20 °C.
no data available
no data available
Reacts with acid anhydrides, acid chlorides, bases and oxidants. Attacks steel, brass and copper.
no data available
Phenols, such as DIBUTYLPHENOL, do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has pKa = 9.88). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases. Such heating may initiate polymerization of the organic compound. Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature). The reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid.
no data available
no data available
no data available
no data available
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The substance is irritating to the eyes, skin and respiratory tract.
no data available
A harmful concentration of airborne particles can be reached quickly when dispersed.
Conversion of 1.1% of the initial concentration of 2,6-di-tert-butylphenol (50 ug) (a further 44.9% was metabolized, but not to completion)(1), 3.5%(2), and 7.7%(3) of the parent compound to CO2 by an activated sludge inoculum was reported over a 5 day time period.
Chlorella, a green algae, had a measured bioaccumulation factor of 800 after exposure to 50 ug/L 2,6-di-tert-butylphenol for 24 hours(1). In fish (Golden Orfe), a bioaccumulation factor of 660 was measured following exposure to 37 ug/L 2,6-di-tert-butylphenol for 3 days(2). An estimated BCF value of 3230 was calculated for 2,6-di-tert-butylphenol(SRC), using an experimental log Kow of 4.92(3) and a recommended regression-derived equation(4). According to a recommended classification scheme(5), these BCF values indicate that bioconcentration in aquatic organisms is an important fate process(SRC).
A Koc of 3600 was measured in river sediment(1). The Koc of 2,6-di-tert-butylphenol is estimated as approximately 11,000(SRC), using an experimental log Kow of 4.92(2) and a regression-derived equation(3,SRC). According to a recommended classification scheme(4), these Koc values suggest that 2,6-di-tert-butylphenol will have slight to no mobility in soil(SRC). Following 5 days incubation, 31.9% of the initial concentration of 2,6-di-tert-butylphenol was present in the non-extractable residue fraction in sludge(5).
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN2810 (For reference only, please check.)
IMDG: UN2810 (For reference only, please check.)
IATA: UN2810 (For reference only, please check.)
ADR/RID: TOXIC LIQUID, ORGANIC, N.O.S. (For reference only, please check.)
IMDG: TOXIC LIQUID, ORGANIC, N.O.S. (For reference only, please check.)
IATA: TOXIC LIQUID, ORGANIC, N.O.S. (For reference only, please check.)
ADR/RID: 6.1 (For reference only, please check.)
IMDG: 6.1 (For reference only, please check.)
IATA: 6.1 (For reference only, please check.)
ADR/RID: I (For reference only, please check.)
IMDG: I (For reference only, please check.)
IATA: I (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available