Skin sensitization, Category 1
Eye irritation, Category 2
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H400 Very toxic to aquatic life
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P264 Wash ... thoroughly after handling.
P273 Avoid release to the environment.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P333+P317 If skin irritation or rash occurs: Get medical help.
P321 Specific treatment (see ... on this label).
P362+P364 Take off contaminated clothing and wash it before reuse.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P391 Collect spillage.
none
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest.
Rinse and then wash skin with water and soap.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Refer for medical attention .
SYMPTOMS: This chemical may cause severe irritation to the skin, eyes, and mucous membranes. ACUTE/CHRONIC HAZARDS: This chemical and its decomposition products are considered to be very toxic by: ingestion, inhalation and skin absorption. It emits toxic fumes. It may react violently with oxidizing materials. It is also known to be a strong skin irritant. (NTP, 1992)
Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Poisons A and B
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Data is not available for this compound. It is probably non-flammable. (NTP, 1992)
In case of fire in the surroundings, use appropriate extinguishing media.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers.
Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Keep tightly closed.
no data available
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles.
Protective gloves.
Avoid inhalation of dust.
no data available
Solid.
White to off white.
Penetrating bromine odor
94.35°C. Remarks:Melting point.
244 °C. Remarks:Unknown whether boiling point is given for standard and pressure.
Not combustible.
no data available
98°C(lit.)
no data available
no data available
no data available
no data available
Slightly soluble (1-10 mg/ml) (NTP, 1992)
log Pow = 3.7. Temperature:23.5 °C.;Pow = 4 600. Temperature:23.5 °C.
0.063 Pa. Temperature:25 °C.
2.618. Temperature:20 °C.
11.4 (vs air)
no data available
Slightly soluble in water.
no data available
2,4,6-TRIBROMOPHENOL can react with oxidizing materials (NTP, 1992).
no data available
no data available
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Hydrogen bromide gas.
no data available
no data available
no data available
no data available
no data available
no data available
The substance is irritating to the eyes.
Repeated or prolonged contact may cause skin sensitization.
A harmful concentration of airborne particles can be reached quickly when dispersed.
AEROBIC: 2,4,6-Tribromophenol, present at 100 mg/L, reached 49% of its theoretical BOD in 4 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test(1). 2,4,6-Tribromophenol was not degraded over 14 days in a marine sediment slurry, prepared from sediment from the 0 to 1 cm interval with equivalent amounts of filtered seawater(2). No ring degradation was reported for 2,4,6-tribromophenol, at 100 mg/L, over a 5-day period using a soil inoculum(3). Water samples collected from two treatment ponds were unable to degrade 2,4,6-tribromophenol over 32 days(4).
BCF values of 513(1,3) and 83(2) were measured in Brachydanio rerio and fathead minnow, respectively, for 2,4,6-tribromophenol. According to a classification scheme(4), these BCF values suggest the potential for bioconcentration in aquatic organisms is moderate to high.
The Koc of 2,4,6-tribromophenol is estimated as 4,200(SRC), using a log Kow of 4.13(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that 2,4,6-tribromophenol is expected to have slight mobility in soil. The pKa of 2,4,6-tribromophenol is 6.80(4), indicating that this compound will partially exist in the anion form in the environment and anions generally do not adsorb more strongly to soils containing organic carbon and clay than their neutral counterparts(5).
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available
Do NOT take working clothes home.