2,3,3,3-Tetrafluoroprop-1-ene SDS
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifier
- Product name： 2,3,3,3-Tetrafluoroprop-1-ene
- CAS： 754-12-1
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses： For R&D use only. Not for medicinal, household or other use.
- Uses advised against： none
Company Identification
- Company：Chemicalbook.in
- Address：5 vasavi Layout Basaveswara Nilayam Pragathi Nagar Hyderabad, India -500090
- Telephone：+91 9550333722
SECTION 2: Hazards identification
Classification of the substance or mixture
Flammable gases, Category 1A, Flammable gas
GHS label elements, including precautionary statements
-
Pictogram(s)
- Signal word Danger
H220 Extremely flammable gas
H280 Contains gas under pressure; may explode if heated
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 In case of leakage, eliminate all ignition sources.
P403 Store in a well-ventilated place.
none
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
Substance
- Chemical name: 2,3,3,3-Tetrafluoroprop-1-ene
- Common names and synonyms: 2,3,3,3-Tetrafluoroprop-1-ene
- CAS number: 754-12-1
- EC number: 616-220-0
- Concentration: 100%
SECTION 4: First aid measures
Description of necessary first-aid measures
Fresh air, rest.
ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .
ON FROSTBITE: rinse with plenty of water. Refer immediately for medical attention.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms/effects, acute and delayed
no data available
Indication of immediate medical attention and special treatment needed, if necessary
no data available
SECTION 5: Firefighting measures
Suitable extinguishing media
Use dry chemical, carbon dioxide or alcohol-resistant foam.
Specific hazards arising from the chemical
Extremely flammable. Cylinder may explode in heat of fire. Gas/air mixtures are explosive.
Special protective actions for fire-fighters
Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with carbon dioxide, dry powder. Combat fire from a sheltered position. In case of fire: keep cylinder cool by spraying with water.
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Evacuate danger area! Consult an expert! Turn off gas at source if possible. Ventilation. Remove gas with fine water spray. NEVER direct water jet on liquid. Personal protection: complete protective clothing including self-contained breathing apparatus.
Environmental precautions
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
Precautions for safe handling
NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding) if in liquid state. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities
Fireproof. Cool. Keep in a well-ventilated room.
SECTION 8: Exposure controls/personal protection
Control parameters
MAK: 950 mg/m3, 200 ppm; peak limitation category: II(2); pregnancy risk group: C
no data available
Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Individual protection measures, such as personal protective equipment (PPE)
Wear face shield or safety goggles.
Cold-insulating gloves.
Use ventilation.
no data available
SECTION 9: Physical and chemical properties and safety characteristics
-
Physical state：
COLOURLESS LIQUEFIED GAS.
-
Colour：
no data available
-
Odour：
no data available
-
Melting point/freezing point：
-152°C
-
Boiling point or initial boiling point and boiling range：
-28°C
-
Flammability：
no data available
-
Lower and upper explosion limit/flammability limit：
no data available
-
Flash point：
no data available
-
Auto-ignition temperature：
405°C
-
Decomposition temperature：
no data available
-
pH：
no data available
-
Kinematic viscosity：
no data available
-
Solubility：
0.2 g/l(very poor)(24°C)
-
Partition coefficient n-octanol/water：
2.15
-
Vapour pressure：
600 kPa(21.1°C)
-
Density and/or relative density：
1.203 g/cm3
-
Relative vapour density：
no data available
-
Particle characteristics：
no data available
SECTION 10: Stability and reactivity
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
The gas is heavier than air and may travel along the ground; distant ignition possible.Decomposes on contact with hot surfaces or flames. This produces toxic fumes including hydrogen fluoride.
Conditions to avoid
no data available
Incompatible materials
no data available
Hazardous decomposition products
no data available
SECTION 11: Toxicological information
Acute toxicity
- Oral: no data available
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
Asphyxiation. Rapid evaporation of the liquid may cause frostbite. See Notes.
STOT-repeated exposure
no data available
Aspiration hazard
On loss of containment this substance can cause suffocation by lowering the oxygen content of the air in confined areas.
SECTION 12: Ecological information
Toxicity
- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Other adverse effects
no data available
SECTION 13: Disposal considerations
Disposal methods
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
UN Number
ADR/RID: UN3161 (For reference only, please check.)
IMDG: UN3161 (For reference only, please check.)
IATA: UN3161 (For reference only, please check.)
UN Proper Shipping Name
ADR/RID: LIQUEFIED GAS, FLAMMABLE, N.O.S. (For reference only, please check.)
IMDG: LIQUEFIED GAS, FLAMMABLE, N.O.S. (For reference only, please check.)
IATA: LIQUEFIED GAS, FLAMMABLE, N.O.S. (For reference only, please check.)
Transport hazard class(es)
ADR/RID: 2.1 (For reference only, please check.)
IMDG: 2.1 (For reference only, please check.)
IATA: 2.1 (For reference only, please check.)
Packing group, if applicable
ADR/RID: (For reference only, please check.)
IMDG: (For reference only, please check.)
IATA: (For reference only, please check.)
Environmental hazards
ADR/RID: No
IMDG: No
IATA: No
Special precautions for user
no data available
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
Safety, health and environmental regulations specific for the product in question
SECTION 16: Other information
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/
Other Information
High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.Check oxygen content before entering the area.Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.