Flammable liquids, Category 2
Acute toxicity - Category 2, Oral
Acute toxicity - Category 1, Dermal
Serious eye damage, Category 1
Acute toxicity - Category 2, Inhalation
Carcinogenicity, Category 1B
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2
H225 Highly flammable liquid and vapour
H300 Fatal if swallowed
H310 Fatal in contact with skin
H318 Causes serious eye damage
H330 Fatal if inhaled
H350 May cause cancer
H411 Toxic to aquatic life with long lasting effects
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P262 Do not get in eyes, on skin, or on clothing.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P284 [In case of inadequate ventilation] wear respiratory protection.
P203 Obtain, read and follow all safety instructions before use.
P273 Avoid release to the environment.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water [or shower].
P370+P378 In case of fire: Use ... to extinguish.
P301+P316 IF SWALLOWED: Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P330 Rinse mouth.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P316 Get emergency medical help immediately.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P317 Get medical help.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P320 Specific treatment is urgent (see ... on this label).
P318 IF exposed or concerned, get medical advice.
P391 Collect spillage.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest. Half-upright position. Refer immediately for medical attention.
First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Do NOT induce vomiting. Refer for medical attention .
Toxic after acute exposure. Can severely irritate eyes, skin, and lungs. (EPA, 1998)
Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary . Monitor for shock and treat if necessary . Anticipate seizures and treat if necessary . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport . Do not use emetics. For ingestion, rinse mouth and administer 5 mg/kg up to 200 ml of water for dilution if the patent can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal . Cover skin bums with dry sterile dressings after decontamination . /Organic bases/Amines and related compounds/
Extinguish with dry chemicals or carbon dioxide. Water may be ineffective on fire. Cool exposed containers with water.
Chemical is extremely flammable; vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion. Avoid acids, strong oxidizers. Thermally unstable. Hazardous polymerization may occur. Contact with acid promotes violent polymerization. (EPA, 1998)
Use water spray, alcohol-resistant foam, dry powder. NO carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. Combat fire from a sheltered position.
Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
PRECAUTIONS FOR "CARCINOGENS": A high-efficiency particulate arrestor or charcoal filters can be used to minimize amt of carcinogen in exhausted air ventilated safety cabinets, lab hoods, glove boxes or animal rooms ... Filter housing that is designed so that used filters can be transferred into plastic bag without contaminating maintenance staff is avail commercially. Filters should be placed in plastic bags immediately after removal ... The plastic bag should be sealed immediately ... The sealed bag should be labelled properly ... Waste liquids ... should be placed or collected in proper containers for disposal. The lid should be secured & the bottles properly labelled. Once filled, bottles should be placed in plastic bag, so that outer surface ... is not contaminated ... The plastic bag should also be sealed & labelled. ... Broken glassware ... should be decontaminated by solvent extraction, by chemical destruction, or in specially designed incinerators. Chemical Carcinogens
NO open flames, NO sparks and NO smoking. NO contact with acids. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Fireproof. Separated from acids, oxidants and food and feedstuffs. Cool. Ventilation along the floor. Store only in original container. Store only if stabilized.Keep containers closed, store in fire-resistive house.
TLV: 0.2 ppm as TWA; 0.4 ppm as STEL; (skin); A3 (confirmed animal carcinogen with unknown relevance to humans).MAK: skin absorption (H); carcinogen category: 2; germ cell mutagen group: 3B
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear face shield or eye protection in combination with breathing protection.
Protective gloves. Protective clothing.
Use closed system.
no data available
Propyleneimine, stabilized is a clear colorless liquid with an ammonia-like odor. Flash point 25°F. Toxic by ingestion, inhalation and through skin absorption. Less dense than water. Vapors are heavier than air. Produces toxic oxides of nitrogen during combustion. Under prolonged exposure to fire or heat the containers may rupture violently and rocket. Used as an organic intermediate.
Colorless, oily liquid.
ODOR LIKE ALIPHATIC AMINES
-65°C
66°C
Class IB Flammable Liquid: Fl.P. below 73°F and BP at or above 100°F.
no data available
-4°C
no data available
no data available
no data available
0.491 cP at 25 deg C
greater than or equal to 100 mg/mL at 66° F (NTP, 1992)
log Kow = 0.13 (est)
112 mm Hg at 68° F (EPA, 1998)
0.8
2 (EPA, 1998) (Relative to Air)
no data available
100 ppm; NIOSH has recommended that propyleneimine be treated as a potential human carcinogen.
The substance may polymerize under the influence of acids. This generates fire or explosion hazard. Decomposes on heating. This produces toxic fumes including nitrogen oxides. Attacks some forms of plastic, coatings and rubber.
no data available
A flammable liquid and very dangerous fire hazard when exposed to heat or flame.The vapour is heavier than air and may travel along the ground; distant ignition possible.PROPYLENEIMINE is subject to violent polymerization on contact with an acid. (The inhibitor is intended to prevent polymerization). Incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides.
no data available
Incompatible with acids, strong oxidizers.
When heated to decomposition it emits toxic fumes of /nitrogen oxide/.
no data available
no data available
no data available
no data available
A3; Confirmed animal carcinogen with unknown relevance to humans.
No information is available on the reproductive or developmental effects of 1,2-propyleneimine in humans or animals.
The substance is severely irritating to the eyes, skin and respiratory tract. Inhalation may cause lung oedema. See Notes. Exposure far above the OEL could cause death.
This substance is possibly carcinogenic to humans.
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.
no data available
An estimated BCF of 3 was calculated for propyleneimine(SRC), using an estimated log Kow of 0.13(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).
Using a structure estimation method based on molecular connectivity indices(1), the Koc for propyleneimine can be estimated to be 25(SRC). According to a classification scheme(2), this estimated Koc value suggests that propyleneimine is expected to have very high mobility in soil(SRC). The pKa of propyleneimine is 8.22(3), indicating that this compound will exist primarily in the protonated form in the environment and cations generally adsorb more strongly to organic carbon and clay than their neutral counterparts(4).
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1921 (For reference only, please check.)
IMDG: UN1921 (For reference only, please check.)
IATA: UN1921 (For reference only, please check.)
ADR/RID: PROPYLENEIMINE, STABILIZED (For reference only, please check.)
IMDG: PROPYLENEIMINE, STABILIZED (For reference only, please check.)
IATA: PROPYLENEIMINE, STABILIZED (For reference only, please check.)
ADR/RID: 3 (For reference only, please check.)
IMDG: 3 (For reference only, please check.)
IATA: 3 (For reference only, please check.)
ADR/RID: I (For reference only, please check.)
IMDG: I (For reference only, please check.)
IATA: I (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available
Explosive limits are unknown in literature, although the substance is combustible and has a flash point < 61°C.Reacts violently with fire extinguishing agents such as carbon dioxide.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.Data on similar substances suggest the possibility of environmental effects.An added stabilizer or inhibitor can influence the toxicological properties of this substance; consult an expert.Do NOT take working clothes home.