Skin corrosion, Sub-category 1C
Skin sensitization, Sub-category 1A
Serious eye damage, Category 1
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H410 Very toxic to aquatic life with long lasting effects
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash ... thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316 Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P333+P317 If skin irritation or rash occurs: Get medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P317 Get medical help.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest. Refer for medical attention.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .
Liquid is irritating to skin, eyes, and mucous membranes. Ingestion may cause nausea. Repeated skin exposure can cause dermatitis and may produce a sensitizing effect. (USCG, 1999)
Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary . Anticipate seizures and treat if necessary . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport . Do not use emetics. For ingestion, rinse mouth and administer 5 m1/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool . Administer activated charcoal . Cover skin burns with dry sterile dressings after decontamination . Sulfur and related compounds
Dry chem, or carbon dioxide. Water or foam may cause frothing. Water may be ineffective on fire. Cool exposed containers with water.
Special Hazards of Combustion Products: Poisonous and irritating gases (e.g., sulfur dioxide) are generated in fires. (USCG, 1999)
Use powder, AFFF, foam, carbon dioxide.
Personal protection: self-contained breathing apparatus. Collect leaking and spilled liquid in sealable containers as far as possible. Carefully collect remainder.
Personal protection: self-contained breathing apparatus. Collect leaking and spilled liquid in sealable containers as far as possible. Carefully collect remainder.
Collect leaking and spilled liquid in sealable containers as far as possible. Carefully collect remainder. Personal protection: self-contained breathing apparatus.
NO open flames. Above 88°C use a closed system and ventilation. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Separated from strong oxidants.Separated from strong oxidants.
TLV: 0.1 ppm as TWA; (SEN)
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles or eye protection in combination with breathing protection.
Protective gloves. Protective clothing.
Use ventilation, local exhaust or breathing protection.
no data available
Lauryl mercaptan is an oily colorless liquid with a mild skunk odor. Freezing point 19°F. (USCG, 1999)
Colorless, water-white, or pale-yellow, oily liquid [Note: A solid below 15 degrees F].
MILD CHARACTERISTIC
-7°C
266-283°C(lit.)
Class IIIA Combustible Liquid: Fl.P. at or above 140°F and below 200°F.
no data available
120°C
no data available
no data available
no data available
no data available
less than 1 mg/mL at 70° F (NTP, 1992)
log Kow = 6.18 (est)
0.00861mmHg at 25°C
0.845g/mLat 25°C(lit.)
7 (vs air)
no data available
Decomposes on burning. This produces toxic gases. Reacts with strong oxidants.
no data available
Combustible when exposed to heat or flame.LAURYL MERCAPTAN is incompatible with bases, oxidizing agents, reducing agents and alkali metals. Easily oxidized to disulfide. (NTP, 1992)
no data available
They will react with water, steam, or acids to produce toxic...vapors... Mercaptans
When heated to decomposition it emits toxic fumes of /sulfur oxides/.
no data available
no data available
no data available
no data available
no data available
no data available
The substance is irritating to the eyes, skin and respiratory tract.
Repeated or prolonged contact may cause skin sensitization.
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.
no data available
An estimated BCF of 360 was calculated for 1-dodecanethiol(SRC), using an estimated log Kow of 6.18(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is moderate(SRC), provided the compound is not metabolized by the organism(SRC).
Using a structure estimation method based on molecular connectivity indices(1), the Koc of 1-dodecanethiol can be estimated to be 1.1X10+4(SRC). According to a classification scheme(2), this estimated Koc value suggests that 1-dodecanethiol is expected to be immobile in soil.
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN3265 (For reference only, please check.)
IMDG: UN3265 (For reference only, please check.)
IATA: UN3265 (For reference only, please check.)
ADR/RID: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (For reference only, please check.)
IMDG: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (For reference only, please check.)
IATA: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (For reference only, please check.)
ADR/RID: 8 (For reference only, please check.)
IMDG: 8 (For reference only, please check.)
IATA: 8 (For reference only, please check.)
ADR/RID: I (For reference only, please check.)
IMDG: I (For reference only, please check.)
IATA: I (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available
Do NOT take working clothes home.