But-1-ene SDS
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifier
- Product name： But-1-ene
- CAS： 106-98-9
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses： For R&D use only. Not for medicinal, household or other use.
- Uses advised against： none
Company Identification
- Company：Chemicalbook.in
- Address：5 vasavi Layout Basaveswara Nilayam Pragathi Nagar Hyderabad, India -500090
- Telephone：+91 9550333722
SECTION 2: Hazards identification
Classification of the substance or mixture
Gases under pressure: Compressed gas
Flammable gases, Category 1A, Flammable gas
GHS label elements, including precautionary statements
-
Pictogram(s)
- Signal word Danger
H220 Extremely flammable gas
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 In case of leakage, eliminate all ignition sources.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P403 Store in a well-ventilated place.
none
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
Substance
- Chemical name: But-1-ene
- Common names and synonyms: But-1-ene
- CAS number: 106-98-9
- EC number: 203-449-2
- Concentration: 100%
SECTION 4: First aid measures
Description of necessary first-aid measures
Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms/effects, acute and delayed
SYMPTOMS: This compound may be an asphyxiant or a slight anesthetic at high concentrations. It may also cause eye irritation. ACUTE/CHRONIC HAZARDS: This material may be narcotic in high concentrations and is an asphyxiant. This chemical is extremely flammable. (NTP, 1992)
Indication of immediate medical attention and special treatment needed, if necessary
Basic Treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... Anticipate seizures and treat as necessary ... For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... Treat frostbite with rapid rewarming techniques ... Aliphatic hydrocarbons and related compounds
SECTION 5: Firefighting measures
Suitable extinguishing media
Fire prevention: to reduce the likelihood of accidental leakage ... reserve valves & automatic closure devices should be provided ... sources of ignition should be prevented & fire-fighting equipment should be provided. hydrocarbons, aliphatic
Specific hazards arising from the chemical
This chemical is flammable. Vapor is heavier than air and may travel long distances to an ignition source and flash back. (NTP, 1992)
Special protective actions for fire-fighters
Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with powder, carbon dioxide. In case of fire: keep cylinder cool by spraying with water. Combat fire from a sheltered position.
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Evacuate danger area! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Remove all ignition sources.
Environmental precautions
Evacuate danger area! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Remove all ignition sources.
Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
Precautions for safe handling
NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities
Fireproof. Cool. Ventilation along the floor.
SECTION 8: Exposure controls/personal protection
Control parameters
TLV: 250 ppm as TWA
no data available
Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Individual protection measures, such as personal protective equipment (PPE)
Wear face shield or eye protection in combination with breathing protection.
Cold-insulating gloves.
Use ventilation.
no data available
SECTION 9: Physical and chemical properties and safety characteristics
-
Physical state：
PHYSICAL DESCRIPTION: Colorless gas. (NTP, 1992)
-
Colour：
Colorless
-
Odour：
Slightly aromatic odor
-
Melting point/freezing point：
-75°C(lit.)
-
Boiling point or initial boiling point and boiling range：
?6.3°C(lit.)
-
Flammability：
Extremely flammable.
-
Lower and upper explosion limit/flammability limit：
Lower flammable limit: 1.6% by volume; Upper flammable limit: 10.0% by volume
-
Flash point：
-80°C
-
Auto-ignition temperature：
723°F
-
Decomposition temperature：
no data available
-
pH：
no data available
-
Kinematic viscosity：
7.76X10-3 mPa sec of saturated vapor at 298.15K; 0.186 mPa sec of saturated liquid at 266 K
-
Solubility：
Insoluble (NTP, 1992)
-
Partition coefficient n-octanol/water：
log Kow= 2.40
-
Vapour pressure：
1939 mm Hg ( 21.1 °C)
-
Density and/or relative density：
0.625 g/cm3
-
Relative vapour density：
1.93 (vs air)
-
Particle characteristics：
no data available
SECTION 10: Stability and reactivity
Reactivity
The substance may polymerize. Reacts violently with oxygen and oxidants. This generates fire and explosion hazard.
Chemical stability
Stable
Possibility of hazardous reactions
Highly flammable ... Dangerous fire ... risk.The gas is heavier than air and may travel along the ground; distant ignition possible.The unsaturated aliphatic hydrocarbons, such as 1-BUTENE, are generally much more reactive than the alkanes. Strong oxidizers may react vigorously with them. Reducing agents can react exothermically to release gaseous hydrogen. In the presence of various catalysts (such as acids) or initiators, compounds in this class can undergo very exothermic addition polymerization reactions. May react with oxidizing materials. Aluminum borohydride reacts with alkenes and in the presence of oxygen, combustion is initiated even in the absence of moisture.
Conditions to avoid
no data available
Incompatible materials
Incompatible with/ oxidizing materials, aluminum tris-tetrahydroborate.
Hazardous decomposition products
When heated to decomposition it emits acrid smoke and fumes.
SECTION 11: Toxicological information
Acute toxicity
- Oral: no data available
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
Rapid evaporation of the liquid may cause frostbite.
STOT-repeated exposure
no data available
Aspiration hazard
On loss of containment this substance can cause suffocation by lowering the oxygen content of the air in confined areas.
SECTION 12: Ecological information
Toxicity
- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
Persistence and degradability
Cell free extracts and suspensions of microorganisms isolated from soil or water and raised on ethylene were found to epoxidize 1-butene to butene-1,2-epoxide(1,2). Methanotrophic bacteria isolated from soil and water were found to epoxidize 1-butene(3). Pure cultures of Pseudomonas oleovorans grown on octane oxidized 1-butene to 1-butene-3-ol(4). Bacteria isolated from soil and water and raised on propane were found to epoxidize 1-butene(5). Alkenes can be utilized by a wide range of microorganisms and are catabolized via several routes(6). These include the oxidation of a terminal methyl group leaving the double bond intact and resulting in unsaturated alcohol, aldehyde and fatty acid or oxidation of the double bond resulting in the formation of epoxide, diol compounds and possibly hydroxyacids(6).
Bioaccumulative potential
An estimated BCF of 14 was calculated for 1-butene(SRC), using a log Kow of 2.40(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low.
Mobility in soil
Using a structure estimation method based on molecular connectivity indices(1), the Koc for 1-butene can be estimated to be 44(SRC). According to a classification scheme(2), this estimated Koc value suggests that 1-butene is expected to have very high mobility in soil.
Other adverse effects
no data available
SECTION 13: Disposal considerations
Disposal methods
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
UN Number
ADR/RID: UN1012 (For reference only, please check.)
IMDG: UN1012 (For reference only, please check.)
IATA: UN1012 (For reference only, please check.)
UN Proper Shipping Name
ADR/RID: BUTYLENE (For reference only, please check.)
IMDG: BUTYLENE (For reference only, please check.)
IATA: BUTYLENE (For reference only, please check.)
Transport hazard class(es)
ADR/RID: 2.1 (For reference only, please check.)
IMDG: 2.1 (For reference only, please check.)
IATA: 2.1 (For reference only, please check.)
Packing group, if applicable
ADR/RID: (For reference only, please check.)
IMDG: (For reference only, please check.)
IATA: (For reference only, please check.)
Environmental hazards
ADR/RID: No
IMDG: No
IATA: No
Special precautions for user
no data available
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
Safety, health and environmental regulations specific for the product in question
SECTION 16: Other information
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/
Other Information
Health effects of exposure to the substance have not been investigated.Check oxygen content before entering area.