Benzyl chloride

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alpha-Chlorotoluene 100-44-7 Benzyl chloride

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alpha-Chlorotoluene CAS 100-44-7

Benzyl chloride CAS 100-44-7

Name:    Benzyl chloride
Synonyms:    ALPHA-CHLOROTOLUENE;AKOS BBS-00003953;(chloromethyl)-benzen;(Chloromethyl)benzene;(chloromethyl)-Benzene;1-Chloromethylbenzene;1-Chlorome-thylbenzene;ai3-15518
CAS:    100-44-7
MF:    C7H7Cl
MW:    126.58
EINECS:    202-853-6
Product Categories:    Aromatics;Intermediates & Fine Chemicals;Pharmaceuticals;Aryl;Building Blocks;C7;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;API Intermediate;alkyl chloride;-;Pharmaceutical Intermediates;Organics;Biochemistry;Reagents for Oligosaccharide Synthesis
Mol File:    100-44-7.mol
Benzyl chloride Structure
Benzyl chloride Chemical Properties
Melting point     -39 °C
Boiling point     179 °C
density     1.1 g/mL at 25 °C(lit.)
vapor density     4.36 (vs air)
vapor pressure     10.3 mm Hg ( 60 °C)
refractive index     n20/D 1.538(lit.)
Fp     165 °F
storage temp.     0-6°C
solubility     soluble0.46g/L at 30°C (Decomposes in contact with water)
form     Liquid
color     Clear colorless to slightly yellow
Odor    Pungent, irritating.
explosive limit    1.1-14%(V)
Water Solubility     0.3 g/L (20 ºC)

 Benzyl chloride, or α-chlorotoluene, is an organic compound with the formula C6H5CH2Cl. This colourless liquid is a reactive organochlorine compound that is a widely used chemical building block.
Synonyms     

Benzyl chloride; α-Chlorotoluene; phenylmethyl chloride; Benzene, (chloromethyl)-; (Chloromethyl)benzene; Expand
CAS No.     100-44-7
Molecular Formula     C7H7Cl
Molecular Weight     126.58300
PSA     0.00000
LogP     2.42540
Properties
Appearance & Physical State     colorless liquid
Density     1.1
Boiling Point     179ºC
Melting Point     -39ºC
Flash Point     67ºC
Refractive Index     1.537-1.539
Water Solubility     0.3 g/L (20 ºC)
Stability     Unstable - inhibitors such as propylene oxide or trimethylamine are usually added to prevent polymerization. Combustible. Incompatible with strong oxidizing agents, water, acids, most common metals, dimethyl sulfoxide. Above flash point vapour-air mixtures
Storage Condition     0-6ºC
Vapor Density     4.36 (vs air)
Vapor Pressure     10.3 mm Hg ( 60 °C)
Safety Info
RTECS     XS8925000
Hazard Class     6.1
Safety Statements     S45-S53
HS Code     2903999090

Safety Information
Hazard Codes     T,T+
Risk Statements     45-22-23-37/38-41-48/22-43-26-46
Safety Statements     53-45-36/37/39-28-26-36/37
RIDADR     UN 1738 6.1/PG 2
WGK Germany     3
RTECS     XS8925000
F     8-19
Autoignition Temperature    585 °C
TSCA     Yes
HazardClass     6.1
PackingGroup     II
HS Code     29039990

 MSDS Information

Benzyl chloride Usage And Synthesis
Chemical Properties    Colorless to yellow liquid
Chemical Properties    Benzyl chloride is a colorless to s lightly yellow liquid with a strong, unpleasant, irritating odor. The Odor Threshold is 0.05 ppm.
Physical properties    Colorless to pale yellowish-brown liquid with a pungent, aromatic, irritating odor. Odor threshold concentration is 47 ppbv (Leonardos et al., 1969). Katz and Talbert (1930) reported an experimental detection odor threshold concentration of 210 μg/m3 (41 ppbv).
Uses    Benzyl chloride is used in the manufacture ofdyes, artificial resins, tanning agents, phar maceuticals, plasticizers, perfumes, lubri cants, and miscellaneous benyl compounds.
Uses    An intermediate in the preparation of phenylacetic acid (precursor to phamaceuticals). Also a precursor molecule to benzyl esters which are used as plasticizer, flavorants, and perfumes.
Uses    manufacture of benzyl Compounds, perfumes, pharmaceutical products, dyes, synthetic tannins, artificial resins.

Benzyl chloride Preparation Products And Raw materials
Preparation Products    Meclozine-->softener DOD-->6-BENZYLAMINOPURINE-->4-(Acetamidomethyl)benzenesulfonylchloride -->Benzyltrimethylammonium chloride-->N-Benzyl-N-ethylaniline-->N-Benzylcinchonidinium chloride-->AMMONIUM O,O-DIISOPROPYLTHIOPHOSPHATE-->Benzyl salicylate-->sodium dibenzyl amine enzene sulfonate-->Benzyl cinnamate-->Benzyl propionate-->4-BENZYLOXY-2-NITROTOLUENE-->Benzyl ether-->4-METHYL-1-PHENYL-2-PENTANOL-->2,3-DIPHENYLPROPIONIC ACID-->ETHYL 5-BENZYLOXYINDOLE-2-CARBOXYLATE-->leucotrope O-->Fast Scarlet Base LG-->Benzyl butyrate-->1-Benzyl-3-hydroxy-1H-indazole-->softener BCH-->2-Benzyl-2-thiopseudourea hydrochloride-->Tetradecyldimethylbenzylammonium chloride-->3-Benzyloxyphenol-->Butyl benzyl phthalate-->pesticide emulsifier BCH-->S-Benzyl-L-cysteine-->4-Benzylpyridine-->azelaic acid, compound with morpholine -->1-Benzyloxy-2-methoxy-4-propenylbenzene -->DIBENZYL PHTHALATE-->Alkyldimethylbenzylammonium chloride-->1,2-Diphenylethane-->Dibenzyl disulfide-->N-BENZYLANTHRANILIC ACID-->Stearyldimethylbenzylammonium chloride-->benzyltrimeehyl ammonium chloride-->Levelling agent S-->4-(phenylmethoxy)azobenzene
Raw materials    Zinc chloride-->2,6-DICHLOROTOLUENE
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