Ethyl formate
| Price | USD1.00 |
| Packge | 1kg |
- Min. Order:1kg
- Supply Ability:100KG
- Time:2019-07-06
Product Details
- Product NameEthyl formate
- CAS No.109-94-4
- EINECS No.203-721-0
- MFC3H6O2
- MW74.08
- InChIKeyWBJINCZRORDGAQ-UHFFFAOYSA-N
- AppearanceLiquidClear
- Boiling point 52-54 °C (lit.)
- density 0.921 g/mL at 20 °C (lit.)
- Melting point -80 °C (lit.)
- Water Solubility 11 g/100 mL (18 ºC)
- storage temp. 2-8°C
AD68
| Ethyl formate Basic information |
| Product Name: | Ethyl formate |
| Synonyms: | FEMA 2434;FORMIC ACID ETHYL ESTER;FORMIC ETHER;ETHYL METHANOATE;ETHYL FORMATE;Aethylformiat;Areginal;Ethyl ester of formic acid |
| CAS: | 109-94-4 |
| MF: | C3H6O2 |
| MW: | 74.08 |
| EINECS: | 203-721-0 |
| Product Categories: | Organics;Analytical Chemistry;Solvents for HPLC & Spectrophotometry;Solvents for Spectrophotometry;Organic synthesis |
| Mol File: | 109-94-4.mol |
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| Ethyl formate Chemical Properties |
| Melting point | −80 °C(lit.) |
| Boiling point | 52-54 °C(lit.) |
| density | 0.921 g/mL at 20 °C(lit.) |
| vapor density | 2.5 (vs air) |
| vapor pressure | 15.16 psi ( 55 °C) |
| refractive index | n20/D 1.359(lit.) |
| FEMA | 2434 | ETHYL FORMATE |
| Fp | 7 °F |
| storage temp. | Flammables area |
| form | Liquid |
| color | Clear |
| explosive limit | 16% |
| Water Solubility | 11 g/100 mL (18 ºC) |
| Sensitive | Moisture Sensitive |
| Merck | 14,3807 |
| BRN | 906769 |
| Stability: | Stable. Extremely flammable. May form explosive mixtures with air. Note low flash point and wide explosive limits. Incompatible with strong oxidizing agents, strong bases, strong acids, nitrates. |
| InChIKey | WBJINCZRORDGAQ-UHFFFAOYSA-N |
| CAS DataBase Reference | 109-94-4(CAS DataBase Reference) |
| NIST Chemistry Reference | Formic acid, ethyl ester(109-94-4) |
| EPA Substance Registry System | Formic acid, ethyl ester(109-94-4) |
| Safety Information |
| Hazard Codes | F,Xn |
| Risk Statements | 11-20/22-36/37 |
| Safety Statements | 9-16-24-26-33 |
| RIDADR | UN 1190 3/PG 2 |
| WGK Germany | 1 |
| RTECS | LQ8400000 |
| TSCA | Yes |
| HazardClass | 3 |
| PackingGroup | II |
| Hazardous Substances Data | 109-94-4(Hazardous Substances Data) |
| Toxicity | LD50 orally in rats: 4.29 g/kg (Smyth) |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| Ethyl formate Usage And Synthesis |
| Chemical Properties | colourless liquid with an aromatic odour |
| Definition | ChEBI: A formate ester resulting from the formal condensation of formic acid with ethanol. |
| Uses | As flavor for lemonades and essences; for manufacture of artificial rum and arrack; also as a solvent for nitrocellulose; as fungicide and larvicide for tobacco, cereals, dried fruits, etc.; in organic synthesis. |
| General Description | A clear colorless liquid with a pleasant odor. Flash point -4°F. Less dense than water. Vapors heavier than air. |
| Air & Water Reactions | Highly flammable. Soluble in water. Slowly decomposed by water to formic acid, a corrosive material and ethyl alcohol, another flammable liquid. |
| Reactivity Profile | Ethyl formate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Ethyl formate is incompatible with the following: Nitrates; strong oxidizers, alkalis & acids [Note: Decomposes slowly in water to form ethyl alcohol and formic acid.] . |
| Hazard | Narcotic and irritant to skin and eyes; use in foods restricted to 0.0015%. Highly flammable, dangerous fire and explosion risk. Questionable carcinogen. |
| Health Hazard | Inhalation of vapor causes slight irritation of the eyes and rapidly increasing irritation of the nose. High concentrations cause deep narcosis within a few minutes followed by death within a few hours. Contact with liquid causes moderate irritation of eyes and mild irritation of skin. Ingestion causes irritation of mouth and stomach; may cause deep narcosis and death if not treated. |
| Fire Hazard | Behavior in Fire: Vapor is heavier than air and may travel long distance to a source of ignition and flash back. |
| Agricultural Uses | Fumigant, Insecticide: Used as a fumigant, especially on dried fruit, Also used as a solvent for cellulose nitrate and acetate and in the production of synthetic flavors. Not currently registered for agricultural use in EU countries and the U.S. Used in Australia and there are 63 global suppliers. |
| Safety Profile | Moderately toxic by ingestion and subcutaneous routes. Mddly toxic by skin contact and inhalation. A powerful inhalation irritant in humans. A skin and eye irritant. Questionable carcinogen with experimental tumorigenic data. Highly flammable liquid. A very dangerous fire and explosion hazard when exposed to heat, flame, or oxilzers. To fight fire, use alcohol foam, spray, mist, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS. |
| Purification Methods | Free acid or alcohol is removed by standing the ester over anhydrous K2CO3, with occasional shaking, then decanting and distilling from P2O5. Alternatively, the ester can be kept over CaH2 for several days, then distilled from fresh CaH2. It cannot be dried with CaCl2 because it reacts rapidly with the ester to form a crystalline compound. [Beilstein 2 IV 23.] |
Company Profile Introduction
Henan CoreyChem Co., Ltd, based on the original Zhengzhou Cote Chemical Research Institute, be brave in absorbing highly educated talents & overseas returnees; actively responded to Zhengzhou City High-tech Zone Government’s Special Care Policy, reorganized and founded in National University of Science and Technology Park, which is a high-tech, stock enterprise of high-end chemical Custom synthesis;The park was created by the People's Government of Henan Province, and proved by Ministry of Education and the National Science & Technology, taking the construction mode of "many college a park, and common development", mainly depends on Zhengzhou University and Henan University’s scientific research and talent advantage to set up Universities, scientific research institute and enterprise scientific research achievements transformation platform, to make high-tech enterprises incubate, is the new high-tech talent gathering base, high and new technology industry enterprise radiation base, colleges and universities technological innovation base.
Henan Coreychem Co., Ltd, facing global High-tech pharmaceutical raw materials, high complex new type intermediates, fine chemicals custom synthesis, scale-up production and Rare chemicals trade. Corey have well-equipped machine, strong technical force and considerate marketing team service. We also have rich experience advantage in basic research, small scale process development, scale-up, industrial technology development & production and cost control.
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- Since:2014-12-17
- Address: No.967,15th Floor,Unit 7, Building 1, No.70 of DianChang Road, High-tech Development Zone, Zhengzho
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