Product Details
- Product Name1,1'-Bis(diphenylphosphino)ferrocene
- CAS No.12150-46-8
- EINECS No.430-420-3
- MFC34H28FeP210*
- MW554.38
- Appearancecrystalyellow to orange
- Melting point 181-182 °C (dec.)(lit.)
- storage temp. 2-8°C
- Water Solubility Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
AD68
| 1,1'-Bis(diphenylphosphino)ferrocene Basic information |
| Reaction |
| Product Name: |
1,1'-Bis(diphenylphosphino)ferrocene |
| Synonyms: |
DPPF;1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE;1,1'-FERROCENEDIYL-BIS(DIPHENYLPHOSPHINE);1,1'-FERROCENEBIS(DIPHENYLPHOSPHINE);1,1'-bis(diphenyphosphino)ferrocene;1,1'-bis(diphenyphosphino)ferrocene(dppf);1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, 97 %;1,1'-Bis(diphenylphosphino)ferrocene,99%DPPF |
| CAS: |
12150-46-8 |
| MF: |
C34H28FeP2 10* |
| MW: |
554.38 |
| EINECS: |
430-420-3 |
| Product Categories: |
Phosphines;Boron, Nitrile, Thio,& TM-Cpds;Miscellaneous;pharmacetical;Ligand;Catalysts-Ligands;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Phosphine Ligands;Synthetic Organic Chemistry;Transition Metal Compounds;Aromatics;Catalyst;Chelating Agents & Ligands;Pharmaceutical intermediates;Achiral Phosphine;Aryl Phosphine |
| Mol File: |
12150-46-8.mol |
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| 1,1'-Bis(diphenylphosphino)ferrocene Chemical Properties |
| |
| 1,1'-Bis(diphenylphosphino)ferrocene Usage And Synthesis |
| Reaction |
- Ligand for Pd-catalyzed cross-coupling.
- Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures.
- Ligand for Ni-catalyzed amination of aryl chlorides.
- Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles.
- Ligand for Ni-catalyzed Suzuki reactions.
- Ni-catalyzed hydroamination of 1,3-dienes.
- Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene.
- Pd-catalyzed γ-arylation of β,γ-unsaturated ketones.
- Ligand for Ru-catalyzed reduction of nitriles to primary amines.
- Ligand for Rh-catalyzed alkyne head-to-tail dimerization.
- Ligand for Rh-catalyzed cross-coupling
- Ligand for Rh-catalyzed olefin isomerization
- Ligand for Ni or Rh-catalyzed borylation
- Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.
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| Chemical Properties |
deep yellow crystalline powder |
| Uses |
suzuki reaction |
| Uses |
Commonly used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which i s a popular reagent for palladium-catalyzed coupling reactions. |
Company Profile
Introduction
Established in 2014,Career Henan Chemical Co. is a manufacturerspecializing in the sale of fine chemicals.
Mainly deals in the sales of:
Pharmaceutical intermediates
OLED intermediates：
Pharmaceutical intermediates;
OLED intermediates;
