TRIBUTYL(1-ETHOXYVINYL)TIN
- CAS NO.：97674-02-7
- Empirical Formula: C16H34OSn
- Molecular Weight: 361.15
- MDL number: MFCD00010240
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-10 11:57:34
What is TRIBUTYL(1-ETHOXYVINYL)TIN?
Chemical properties
Clear colorless liquid
The Uses of TRIBUTYL(1-ETHOXYVINYL)TIN
Electrophilic methyl ketone equivalent used in a recent synthesis of a 13-oxophorbine (chlorophyll) from the corresponding 13-bromochlorin.
General Description
This vinylstannane undergoes Stille coupling with a vinyl triflate, giving, after hydrolysis, an α,β?unsaturated ketone, thus acting as an acetyl anion equivalent.
Properties of TRIBUTYL(1-ETHOXYVINYL)TIN
| Melting point: | <0°C |
| Boiling point: | 85-86 °C0.1 mm Hg(lit.) |
| Density | 1.069 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | >230 °F |
| storage temp. | 2-8°C |
| solubility | Choroform (Slightly), Ethyl Acetate (Slightly) |
| form | liquid |
| color | colorless |
| Specific Gravity | 1.069 |
| Sensitive | Moisture Sensitive |
Safety information for TRIBUTYL(1-ETHOXYVINYL)TIN
| Signal word | Danger |
| Pictogram(s) |
 Skull and Crossbones Acute Toxicity GHS06  Health Hazard GHS08  Environment GHS09 |
| GHS Hazard Statements |
H301:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H372:Specific target organ toxicity, repeated exposure H400:Hazardous to the aquatic environment, acute hazard |
| Precautionary Statement Codes |
P273:Avoid release to the environment. P314:Get medical advice/attention if you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for TRIBUTYL(1-ETHOXYVINYL)TIN
| InChIKey | HGXJOXHYPGNVNK-UHFFFAOYSA-N |
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