TRI(2-FURYL)PHOSPHINE
Synonym(s):TFP;Tri-2-furanylphosphine;Tris(2-furanyl)phosphine;Tris(o-furyl)phosphine
- CAS NO.：5518-52-5
- Empirical Formula: C12H9O3P
- Molecular Weight: 232.17
- MDL number: MFCD00151857
- EINECS: 628-036-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-11-08 17:00:29
What is TRI(2-FURYL)PHOSPHINE?
Chemical properties
TRI(2-FURYL)PHOSPHINE is white to light yellow crystal powde
The Uses of TRI(2-FURYL)PHOSPHINE
TRI(2-FURYL)PHOSPHINE is a phopshine ligand used in transition-metal mediated organic synthesis, in particular in wittig reactions to improved (Z) selectivity.
The Uses of TRI(2-FURYL)PHOSPHINE
suzuki reaction
Properties of TRI(2-FURYL)PHOSPHINE
| Melting point: | 59-64 °C (lit.) |
| Boiling point: | 136 °C/4 mmHg (lit.) |
| Flash point: | 136°C/4mm |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| form | solid |
| color | faintly brown |
| Sensitive | air sensitive |
| BRN | 1577564 |
| InChI | InChI=1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H |
| CAS DataBase Reference | 5518-52-5(CAS DataBase Reference) |
Safety information for TRI(2-FURYL)PHOSPHINE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for TRI(2-FURYL)PHOSPHINE
| InChIKey | DLQYXUGCCKQSRJ-UHFFFAOYSA-N |
| SMILES | P(C1=CC=CO1)(C1=CC=CO1)C1=CC=CO1 |
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