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HomeProduct name listThiomorpholine

Thiomorpholine

Synonym(s):Tetrahydro-2H-1,4-thiazine;Thiamorpholine

  • CAS NO.:123-90-0
  • Empirical Formula: C4H9NS
  • Molecular Weight: 103.19
  • MDL number: MFCD00005974
  • EINECS: 204-660-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
Thiomorpholine Structural

What is Thiomorpholine?

Chemical properties

Clear colorless to yellow liquid

The Uses of Thiomorpholine

Thiomorpholine is used as an intermediate for blonanserin. It is used in the preparation of pyrrole derivatives, which acts as a antimycobacterial agent. It is further involved in the hypocholesterolemic activity.

The Uses of Thiomorpholine

Organic synthesis.

Definition

ChEBI: A saturated organic heteromonocyclic parent that is an analogue of morpholine where the oxygen atom is replaced by sulfur.

General Description

Thiomorpholine forms complexes with Cu(II), Pt(II) and Ni(II) salts and their catalytic activity has been investigated.

Purification Methods

Purify it by vacuum distillation. The hydrochloride has m 179o (from isoPrOH or EtOH/Et2O/HCl). [Davies J Chem Soc 306 1920, Beilstein 27 II 4, 2 III/IV 636.]

Properties of Thiomorpholine

Melting point: 166-168
Boiling point: 169 °C (lit.)
Density  1.026 g/mL at 25 °C (lit.)
refractive index  n20/D 1.538(lit.)
Flash point: 140 °F
storage temp.  under inert gas (nitrogen or Argon) at 2–8 °C
solubility  organic solvents: miscible(lit.)
form  clear liquid
pka 9.14±0.20(Predicted)
color  Colorless to Light yellow to Light orange
Water Solubility  Miscible with waterMiscible with water and organic solvents.
Sensitive  Air Sensitive
Merck  14,9300
BRN  102550
CAS DataBase Reference 123-90-0(CAS DataBase Reference)
NIST Chemistry Reference Thiomorpholine(123-90-0)

Safety information for Thiomorpholine

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P501:Dispose of contents/container to..…

Computed Descriptors for Thiomorpholine

InChIKey BRNULMACUQOKMR-UHFFFAOYSA-N

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