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HomeProduct name listTETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Synonym(s):Copper(I) tetrakis(acetonitrile) hexafluorophosphate;Cuprous tetrakis(acetonitrile) hexafluorophosphate

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Structural

What is TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE?

The Uses of TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:

  • For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
  • To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
  • To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
  • For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.

Properties of TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Melting point: 160 °C (dec.) (lit.)
storage temp.  Inert atmosphere,Store in freezer, under -20°C
form  solid
color  white to light blue
Sensitive  air sensitive, moisture sensitive

Safety information for TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313:IF SKIN irritation occurs: Get medical advice/attention.
P337+P313:IF eye irritation persists: Get medical advice/attention.

Computed Descriptors for TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

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