TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Synonym(s):Copper(I) tetrakis(acetonitrile) hexafluorophosphate;Cuprous tetrakis(acetonitrile) hexafluorophosphate

CAS NO.：64443-05-6
Empirical Formula: C8H12CuF6N4P
Molecular Weight: 372.72
MDL number: MFCD00064810
SAFETY DATA SHEET (SDS)
Update Date: 2023-04-23 13:52:06

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Structural

What is TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE?

The Uses of TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:

For the formation of Cu₂S/CdS nanorod junctions by cationic exchange process.
To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF₆]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
For the synthesis of [Cu(NHC)₂]PF₆ complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.

Properties of TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Melting point:	160 °C (dec.) (lit.)
storage temp.	Inert atmosphere,Store in freezer, under -20°C
form	solid
color	white to light blue
Sensitive	air sensitive, moisture sensitive

Safety information for TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation
Precautionary Statement Codes	P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention.