tert-Butyldimethylsilane
- CAS NO.：29681-57-0
- Empirical Formula: C6H16Si
- Molecular Weight: 116.28
- MDL number: MFCD00010754
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-01 18:09:03
What is tert-Butyldimethylsilane?
The Uses of tert-Butyldimethylsilane
Tert-Butyldimethylsilane (t-BuMe2SiH) is widely used for the protection of hydroxy groups in sugars. Its oxidation product, tert-butyldimethylsilyl hydroperoxide (t-BuMe2SiOOH), is used for preparing luminiscent sources and prostanoids, specifically clavulons[1].
References
[1] D. S. Lutsik-Maksim. “Liquid-phase oxidation of tert-butyldimethylsilane.” Russian Journal of General Chemistry 74 10 (2004): 1508–1512.
Properties of tert-Butyldimethylsilane
| Melting point: | 13°C |
| Boiling point: | 81-83 °C (lit.) |
| Density | 0.701 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | −9 °F |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Specific Gravity | 0.701 |
| Hydrolytic Sensitivity | 3: reacts with aqueous base |
| BRN | 2231162 |
| CAS DataBase Reference | 29681-57-0 |
Safety information for tert-Butyldimethylsilane
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H225:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for tert-Butyldimethylsilane
| InChIKey | QCIWZIYBBNEPKB-UHFFFAOYSA-N |
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