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HomeProduct name listStannous octoate

Stannous octoate

Synonym(s):2-Ethylhexanoic acid tin(II) salt;Stannous 2-ethylhexanoate;Stannous octoate

  • CAS NO.:301-10-0
  • Empirical Formula: C16H30O4Sn
  • Molecular Weight: 405.12
  • MDL number: MFCD00002676
  • EINECS: 206-108-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-08-15 17:37:19
Stannous octoate Structural

What is Stannous octoate?

Chemical properties

White or light yellowish brown paste. Soluble in petroleum ether, insoluble in water. low toxicity of Stannous octoate, oral acute poisoning data of rats LD50=3400mg/kg. acute percutaneous poisoning data of rabbits LD50>2000mg/kg.

The Uses of Stannous octoate

Stannous octoate is susceptible to hydrolysis and oxidation and cannot be used in combination polyethers (premixes). Its catalytic activity is higher than that of dibutyltin dilaurate.
Stannous octoate can be used as a catalyst for polyurethane, mainly in the production of soft block polyether type polyurethane foam, but also as a catalyst for polyurethane coatings, elastomers, room temperature curing silicone rubber, etc. As it is a divalent tin compound, it may be oxidized to tetravalent tin compound itself after foaming, and it remains in the foam body to play the role of an antioxidant, which stays in the foam after foaming and has no adverse effect on the foam performance.

The Uses of Stannous octoate

Tin(II) 2-ethylhexanoate is used as a polymerization initiator in polylactic acid production. It acts as an intermediate as well as a catalyst for urethane foams, lubricants, addition agents and stabilizers for transformer oils.

The Uses of Stannous octoate

A catalyst for polylactide polymerization.

What are the applications of Application

Tin(II) 2-ethylhexanoate is a polymerization catalyst

Preparation

Stannous octoate is produced by reacting 2-ethylhexanoic acid with sodium hydroxide to form sodium 2-ethylhexanoate, which then undergoes a complex decomposition reaction with stannous chloride by heating in an inert solvent.

Hazard

Toxic material.

Flammability and Explosibility

Non flammable

Toxicology

Stannous octoate has influence to human health. It may cause an allergic skin reaction, and serious eye damage. In addition, it is suspected of damaging fertility or the unborn child, and harmful to aquatic life with long lasting effects.

Properties of Stannous octoate

Melting point: <-20°C
Boiling point: >200°C
Density  1.251 g/mL at 25 °C(lit.)
vapor pressure  0.3Pa at 20℃
refractive index  n20/D 1.493(lit.)
Flash point: >110°C
form  liquid
pka 5.09[at 20 ℃]
Specific Gravity 1.251
color  viscous
Water Solubility  Miscible with water.
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
Exposure limits ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference 301-10-0(CAS DataBase Reference)
EPA Substance Registry System Stannous 2-ethylhexanoate (301-10-0)

Safety information for Stannous octoate

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H317:Sensitisation, Skin
H318:Serious eye damage/eye irritation
H361:Reproductive toxicity
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P201:Obtain special instructions before use.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for Stannous octoate

InChIKey KSBAEPSJVUENNK-UHFFFAOYSA-L

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