(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
- CAS NO.:791616-62-1
- Empirical Formula: C36H17F12O4P
- Molecular Weight: 772.47
- MDL number: MFCD08689863
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&?
The Uses of (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
As a chiral Bronsted acid, BINOL- derived cyclic phosphoric acid (such as Akiyama chiral Bronsted acid) was also shown to be an efficient catalyst for the hydrophosphonylation of aldimines at room temperature.
General Description
(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate is a BINOL-based chiral phosphoric acid, which can efficiently catalyze the nucleophilic addition to imine substrates. [BINOL=1,1′-bi-2-naphthol]
Properties of (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
Melting point: | 162-175 °C |
Boiling point: | 722.1±70.0 °C(Predicted) |
Density | 1.63±0.1 g/cm3(Predicted) |
storage temp. | 2-8°C |
form | Powder |
pka | 1.09±0.20(Predicted) |
color | white to light-yellow |
optical activity | [α]20/D -220°, c = 1 in chloroform (typical) |
Safety information for (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
InChIKey | DQORDVSQWPKAQJ-UHFFFAOYSA-N |
New Products
4-Fluorophenylacetic acid 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate (6-METHYL-[1,3]DITHIOLO[4,5-b]QUINOXALIN-2-ONE INDAZOLE-3-CARBOXYLIC ACID 4-IODO BENZOIC ACID (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5,6-Dimethoxyindanone 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 2-aminopropyl benzoate hydrochloride 1-(4-(aminomethyl)benzyl)urea hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
R-5,5',6,6',7,7',8,8'-octahydro-3,3'-diphenyl-[1,1'-Binaphthalene]-2,2'-diol
R-3,3'-bis((3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
R-3,3'-bis[4-(2-naphthalenyl)phenyl]-1,1'-Binaphthalene]-2,2'-diol
(S)-3,3'-DI(ANTHRACEN-9-YL)-1,1'-BINAPHTHYL-2,2'-DIOL
(S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate
(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&
(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
R- 4-oxide--hydroxy-2,6-bis[4-(2-naphthalenyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
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