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HomeProduct name list(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Structural

What is (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&?

The Uses of (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

As a chiral Bronsted acid, BINOL- derived cyclic phosphoric acid (such as Akiyama chiral Bronsted acid) was also shown to be an efficient catalyst for the hydrophosphonylation of aldimines at room temperature.

General Description

(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate is a BINOL-based chiral phosphoric acid, which can efficiently catalyze the nucleophilic addition to imine substrates. [BINOL=1,1′-bi-2-naphthol]

Properties of (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

Melting point: 162-175 °C
Boiling point: 722.1±70.0 °C(Predicted)
Density  1.63±0.1 g/cm3(Predicted)
storage temp.  2-8°C
form  Powder
pka 1.09±0.20(Predicted)
color  white to light-yellow
optical activity [α]20/D -220°, c = 1 in chloroform (typical)

Safety information for (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

InChIKey DQORDVSQWPKAQJ-UHFFFAOYSA-N

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