(R)-(+)-1-Phenylethylamine
Synonym(s):(R)-(+)-1-Phenylethylamine;(R)-(+)-1-Phenylethylamine;D-α-Methylbenzylamine
- CAS NO.：3886-69-9
- Empirical Formula: C8H11N
- Molecular Weight: 121.18
- MDL number: MFCD00064405
- EINECS: 223-423-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-29 11:48:30
What is (R)-(+)-1-Phenylethylamine?
Chemical properties
Colorless to light yellow liqui
The Uses of (R)-(+)-1-Phenylethylamine
(R)-(+)-1-Phenylethylamine is a chiral amine used for the determination of the enantiomeric purity of acids.
The Uses of (R)-(+)-1-Phenylethylamine
(R)-(+)-a-Methylbenzylamine also known as (R)-(+)-1-Phenylethylamine may be used in resolution of a chiral arylalkylamine involving high-conversion enantioselective condensation with capric acid followed by hydrolysis to yield corresponding (R)-(+)-amide.
Definition
ChEBI: The (R)-enantiomer of 1-phenylethanamine.
General Description
(R)-(+)-α-Methylbenzylamine is a chiral amine.
Flammability and Explosibility
Non flammable
Purification Methods
Dissolve the amine in toluene, dry over NaOH and distil; fraction boiling at 187-188o/atm is collected. Store it under N2 to avoid forming the carbamate and urea. Similarly for the S-(-) enantiomer [2627-86-3]. [Ingersoll Org Synth Coll Vol II 503 1943, Robinson & Snyder Org Synth Coll Vol III 717 1955, Beilstein 12 IV 2424, 2425.]
Properties of (R)-(+)-1-Phenylethylamine
| Melting point: | -10 °C |
| Boiling point: | 187-189 °C(lit.) |
| alpha | 40 º (neat) |
| Density | 0.952 g/mL at 20 °C(lit.) |
| vapor pressure | 0.5 mm Hg ( 20 °C) |
| refractive index | n |
| Flash point: | 175 °F |
| storage temp. | 2-8°C |
| solubility | 40g/l |
| form | Liquid |
| pka | 9.04±0.10(Predicted) |
| color | Clear colorless |
| PH | >7 (40g/l, H2O, 20℃) |
| optical activity | [α]23/D +38°, neat |
| Water Solubility | 40 g/L (20 ºC) |
| Sensitive | Air Sensitive |
| Merck | 14,6026 |
| BRN | 2410916 |
| CAS DataBase Reference | 3886-69-9(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzenemethanamine, «alpha»-methyl-, (R)-(3886-69-9) |
| EPA Substance Registry System | Benzenemethanamine, .alpha.-methyl-, (.alpha.R)- (3886-69-9) |
Safety information for (R)-(+)-1-Phenylethylamine
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P270:Do not eat, drink or smoke when using this product. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (R)-(+)-1-Phenylethylamine
| InChIKey | RQEUFEKYXDPUSK-SSDOTTSWSA-N |
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