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HomeProduct name listMN(TMHD)3

MN(TMHD)3

Synonym(s):Mn(dpm)3;Mn(TMHD)3;Shenvi Hydrogenation Catalyst;Tris(dipivaloylmethanato)manganese

MN(TMHD)3 Structural

What is MN(TMHD)3?

The Uses of MN(TMHD)3

Catalyst for:

  • Intramolecular Diels-Alder reactions
  • Single electron donor for excess electron transfer studies in DNA
  • Enantioselective synthesis
  • Borylation reactions
  • Hydrohydrazination and hydroazidation
  • Oxidative carbonylation of phenol

Properties of MN(TMHD)3

Melting point: 165°C
Boiling point: 255°C
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
form  crystal
color  black
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions

Safety information for MN(TMHD)3

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for MN(TMHD)3

InChIKey ORZPLLPBZHORSD-LWTKGLMZSA-K

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