MN(TMHD)3
Synonym(s):Mn(dpm)3;Mn(TMHD)3;Shenvi Hydrogenation Catalyst;Tris(dipivaloylmethanato)manganese
- CAS NO.:14324-99-3
- Empirical Formula: C33H57MnO6
- Molecular Weight: 604.74
- MDL number: MFCD00269825
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is MN(TMHD)3?
The Uses of MN(TMHD)3
Catalyst for:
- Intramolecular Diels-Alder reactions
- Single electron donor for excess electron transfer studies in DNA
- Enantioselective synthesis
- Borylation reactions
- Hydrohydrazination and hydroazidation
- Oxidative carbonylation of phenol
Properties of MN(TMHD)3
Melting point: | 165°C |
Boiling point: | 255°C |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
form | crystal |
color | black |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
Safety information for MN(TMHD)3
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for MN(TMHD)3
InChIKey | ORZPLLPBZHORSD-LWTKGLMZSA-K |
New Products
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ND(TMHD)3
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)SAMARIUM(III)
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)YTTERBIUM
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)SCANDIUM(III)
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III)
PR(TMHD)3
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)YTTRIUM(III)
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)COBALT (III)
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