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HomeProduct name listMETHYL PHENYLPROPIOLATE

METHYL PHENYLPROPIOLATE

METHYL PHENYLPROPIOLATE Structural

What is METHYL PHENYLPROPIOLATE?

Chemical properties

clear colorless to pale yellow liquid

The Uses of METHYL PHENYLPROPIOLATE

Methyl phenylpropiolate may be used in the synthesis of:

  • bicyclohexadienes
  • cis-methyl cinnamate
  • (E)-alkyl 3-(dialkoxyphosphoryl)-3-phenylacrylate derivatives

Synthesis Reference(s)

The Journal of Organic Chemistry, 52, p. 4859, 1987 DOI: 10.1021/jo00231a007
Tetrahedron Letters, 21, p. 849, 1980 DOI: 10.1016/S0040-4039(00)71522-X

General Description

Organoiron carbonyl complexes are obtained by reacting methyl phenylpropiolate with Fe2(CO)9.

Properties of METHYL PHENYLPROPIOLATE

Melting point: 26°C
Boiling point: 109-112 °C/2 mmHg (lit.)
Density  1.086 g/mL at 25 °C (lit.)
refractive index  n20/D 1.5590(lit.)
Flash point: >230 °F
storage temp.  Inert atmosphere,Room Temperature
form  Liquid After Melting
color  Clear colorless to pale yellow
BRN  472813
CAS DataBase Reference 4891-38-7(CAS DataBase Reference)

Safety information for METHYL PHENYLPROPIOLATE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313:IF SKIN irritation occurs: Get medical advice/attention.
P337+P313:IF eye irritation persists: Get medical advice/attention.

Computed Descriptors for METHYL PHENYLPROPIOLATE

InChIKey JFGWPXKGINUNDH-UHFFFAOYSA-N

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