Methyl 2-furoate
Synonym(s):Methyl furan-2-carboxylate;Methyl pyromucate
- CAS NO.:611-13-2
- Empirical Formula: C6H6O3
- Molecular Weight: 126.11
- MDL number: MFCD00003236
- EINECS: 210-254-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-18 21:14:07
What is Methyl 2-furoate ?
Description
Methyl 2-furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy. May be prepared from 2-furoic acid in methanol solution in the presence of HCL as catalyst (oxidation or Carmizzaro reaction).
Chemical properties
Colorless to light yellow liqui
Chemical properties
Methyl furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy
Occurrence
Reported found in cranberry, guava, baked potato, raisin, papaya, blackberry, baked potato, tomato, cognac, coffee, filbert, peanut, cocoa, passion fruit, almonds, tamarind, soursop, dried bonito, kiwifruit, mountain papaya, wild rice, okra, grape brandy and roasted hazelnut.
The Uses of Methyl 2-furoate
Methyl 2-furoate (Methyl furan-2-carboxylate, Methyl pyromucate) was used to synthesize cis-fused 5-oxofuro[2,3-b]furans. It was also used in the preparation of sesquiterpene lactone.
The Uses of Methyl 2-furoate
Solvent, organic synthesis.
Preparation
From 2-furoic acid in methanol solution in the presence of HCl as catalyst (oxidation or Carmizzaro reaction)
Definition
ChEBI: Methyl 2-Furancarboxylate is a carboxylic ester. It is functionally related to a 2-furoic acid.
Aroma threshold values
Aroma characteristics at 1.0%: musty, sweet caramel, fruity, cocoa, bready and slightly rubbery.
Taste threshold values
Taste characteristics at 20 ppm: brothy, yeasty, caramellic and burnt with a sweet bready, acetoin, buttery nuance
Synthesis Reference(s)
Chemical and Pharmaceutical Bulletin, 37, p. 3225, 1989 DOI: 10.1248/cpb.37.3225
General Description
Methyl 2-furoate has been identified as one of the volatile flavor compounds in tequila, okra, berrycactus and black currant juice.
Safety Profile
Poison by intraperitoneal route. A skin irritant and lachrymator. When heated to decomposition it emits acrid smoke and irritating fumes.
Properties of Methyl 2-furoate
Boiling point: | 181 °C (lit.) |
Density | 1.179 g/mL at 25 °C (lit.) |
refractive index | n |
FEMA | 2703 | METHYL 2-FUROATE |
Flash point: | 164 °F |
storage temp. | Inert atmosphere,Room Temperature |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | Liquid |
color | Clear pale yellow to brown |
Odor | fruity, mushroom-like odor |
Water Solubility | slightly soluble |
Sensitive | Lachrymatory |
JECFA Number | 746 |
Merck | 14,4307 |
BRN | 111110 |
CAS DataBase Reference | 611-13-2(CAS DataBase Reference) |
NIST Chemistry Reference | Methyl 2-furoate(611-13-2) |
EPA Substance Registry System | 2-Furancarboxylic acid, methyl ester (611-13-2) |
Safety information for Methyl 2-furoate
Signal word | Danger |
Pictogram(s) |
Skull and Crossbones Acute Toxicity GHS06 |
GHS Hazard Statements |
H301:Acute toxicity,oral H312:Acute toxicity,dermal H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Methyl 2-furoate
Abamectin manufacturer
ALTRAKEM PHARMA LIFE SCIENCES PRIVATE LIMITED
JSK Chemicals
ALS INDIA LIFE SCIENCES
Galaxy Laboratories Private Limited
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