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HomeProduct name listMethyl 2-furoate

Methyl 2-furoate

Synonym(s):Methyl furan-2-carboxylate;Methyl pyromucate

  • CAS NO.:611-13-2
  • Empirical Formula: C6H6O3
  • Molecular Weight: 126.11
  • MDL number: MFCD00003236
  • EINECS: 210-254-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-18 21:14:07
Methyl 2-furoate  Structural

What is Methyl 2-furoate ?

Description

Methyl 2-furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy. May be prepared from 2-furoic acid in methanol solution in the presence of HCL as catalyst (oxidation or Carmizzaro reaction).

Chemical properties

Colorless to light yellow liqui

Chemical properties

Methyl furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy

Occurrence

Reported found in cranberry, guava, baked potato, raisin, papaya, blackberry, baked potato, tomato, cognac, coffee, filbert, peanut, cocoa, passion fruit, almonds, tamarind, soursop, dried bonito, kiwifruit, mountain papaya, wild rice, okra, grape brandy and roasted hazelnut.

The Uses of Methyl 2-furoate

Methyl 2-furoate (Methyl furan-2-carboxylate, Methyl pyromucate) was used to synthesize cis-fused 5-oxofuro[2,3-b]furans. It was also used in the preparation of sesquiterpene lactone.

The Uses of Methyl 2-furoate

Solvent, organic synthesis.

Preparation

From 2-furoic acid in methanol solution in the presence of HCl as catalyst (oxidation or Carmizzaro reaction)

Definition

ChEBI: Methyl 2-Furancarboxylate is a carboxylic ester. It is functionally related to a 2-furoic acid.

Aroma threshold values

Aroma characteristics at 1.0%: musty, sweet caramel, fruity, cocoa, bready and slightly rubbery.

Taste threshold values

Taste characteristics at 20 ppm: brothy, yeasty, caramellic and burnt with a sweet bready, acetoin, buttery nuance

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 37, p. 3225, 1989 DOI: 10.1248/cpb.37.3225

General Description

Methyl 2-furoate has been identified as one of the volatile flavor compounds in tequila, okra, berrycactus and black currant juice.

Safety Profile

Poison by intraperitoneal route. A skin irritant and lachrymator. When heated to decomposition it emits acrid smoke and irritating fumes.

Properties of Methyl 2-furoate

Boiling point: 181 °C (lit.)
Density  1.179 g/mL at 25 °C (lit.)
refractive index  n20/D 1.487(lit.)
FEMA  2703 | METHYL 2-FUROATE
Flash point: 164 °F
storage temp.  Inert atmosphere,Room Temperature
solubility  Chloroform (Slightly), Methanol (Slightly)
form  Liquid
color  Clear pale yellow to brown
Odor fruity, mushroom-like odor
Water Solubility  slightly soluble
Sensitive  Lachrymatory
JECFA Number 746
Merck  14,4307
BRN  111110
CAS DataBase Reference 611-13-2(CAS DataBase Reference)
NIST Chemistry Reference Methyl 2-furoate(611-13-2)
EPA Substance Registry System 2-Furancarboxylic acid, methyl ester (611-13-2)

Safety information for Methyl 2-furoate

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H301:Acute toxicity,oral
H312:Acute toxicity,dermal
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Methyl 2-furoate

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