m-Tolunitrile
Synonym(s):3-Methylbenzonitrile
- CAS NO.：620-22-4
- Empirical Formula: C8H7N
- Molecular Weight: 117.15
- MDL number: MFCD00001808
- EINECS: 210-631-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-24 19:19:26
What is m-Tolunitrile?
Chemical properties
CLEAR COLOURLESS TO VERY SLIGHTLY YELLOW LIQUID
General Description
Clear, yellow liquid.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Nitriles, such as m-Tolunitrile, may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids.
Health Hazard
ACUTE/CHRONIC HAZARDS: m-Tolunitrile causes skin irritation on contact.
Fire Hazard
m-Tolunitrile is combustible.
Purification Methods
Dry the nitrile with MgSO4, fractionally distil it, then wash it with aqueous acid to remove possible traces of amines, dry and redistil it. [Beilstein 9 H 477, 9 I 191, 9 II 325, 9 III 2324, 9 IV 1717.]
Properties of m-Tolunitrile
| Melting point: | −23 °C(lit.) |
| Boiling point: | 99-101 °C20 mm Hg(lit.) |
| Density | 0.976 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 188 °F |
| form | Liquid |
| color | Clear colorless to very slightly yellow |
| Water Solubility | <0.1 g/100 mL at 25 ºC |
| BRN | 507391 |
| CAS DataBase Reference | 620-22-4(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzonitrile, 3-methyl-(620-22-4) |
| EPA Substance Registry System | m-Tolunitrile (620-22-4) |
Safety information for m-Tolunitrile
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H303:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for m-Tolunitrile
| InChIKey | BOHCMQZJWOGWTA-UHFFFAOYSA-N |
Abamectin manufacturer
JSK Chemicals
Dr R R Organics
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