ETHYL PHENYLCYANOACETATE
- CAS NO.：4553-07-5
- Empirical Formula: C11H11NO2
- Molecular Weight: 189.21
- MDL number: MFCD00001866
- EINECS: 224-921-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is ETHYL PHENYLCYANOACETATE?
Chemical properties
clear colorless to light yellow liquid
The Uses of ETHYL PHENYLCYANOACETATE
Ethyl phenylcyanoacetate?is a reagent used for the asymmetric synthesis of?(-)-manzacidin A.?It is also a useful reagent for C-C bond formation by conjugate additions with vinyl sulfones.
Definition
ChEBI: An alpha-substituted cyanoacetate ester that consists of ethyl cyanoacetate bearing an alpha-phenyl substituent.
Synthesis Reference(s)
Journal of the American Chemical Society, 64, p. 576, 1942 DOI: 10.1021/ja01255a033
Organic Syntheses, Coll. Vol. 4, p. 461, 1963
Synthesis, p. 67, 1983
Properties of ETHYL PHENYLCYANOACETATE
| Melting point: | 115-116 °C |
| Boiling point: | 275 °C (lit.) |
| Density | 1.09 g/mL at 25 °C (lit.) |
| refractive index | 1.5033-1.5053 |
| Flash point: | >110°C |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform, DMSO, Methanol (Slightly) |
| form | Liquid |
| color | Clear colorless to light yellow |
| BRN | 611232 |
| CAS DataBase Reference | 4553-07-5(CAS DataBase Reference) |
Safety information for ETHYL PHENYLCYANOACETATE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for ETHYL PHENYLCYANOACETATE
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product: Ethyl phenylcyanoacetate 98%
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