Diphenyl carbonate
Synonym(s):Di-2-pyridylketone-4-cyclohexyl-4-methyl-3-thiosemicarbazone
- CAS NO.：102-09-0
- Empirical Formula: C13H10O3
- Molecular Weight: 214.22
- MDL number: MFCD00003037
- EINECS: 203-005-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:57
What is Diphenyl carbonate?
Chemical properties
white solid
The Uses of Diphenyl carbonate
Estrogenic activity of Diphenyl Carbonate by yeast 2-hybrid assay was studied.
The Uses of Diphenyl carbonate
In the molten state as solvent for nitrocellulose.
Definition
ChEBI: A carbonate ester that is the diphenyl ester of carbonic acid.
Preparation
Diphenyl carbonate is prepared by passing phosgene into a solution of
phenol in aqueous sodium hydroxide in the presence of an inert solvent such
as methylene chloride:
The organic phase, which contains the diphenyl carbonate, is separated; the solvent is stripped off and the diphenyl carbonate is purified by distillation. The reaction is accelerated by tertiary amines and is analogous to the interfacial polycondensation of 2,2-bis(4'hydroxyphenyl)propane and phosgene described. Diphenyl carbonate is a white crystalline solid, m.p. 78??C.
Flammability and Explosibility
Non flammable
Safety Profile
Questionable carcinogen with experimental neoplastigenic and tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes
Properties of Diphenyl carbonate
| Melting point: | 79-82 °C (lit.) |
| Boiling point: | 301-302 °C (lit.) |
| Density | 1,3 g/cm3 |
| vapor pressure | 0.014Pa at 20℃ |
| refractive index | 1.5090 (estimate) |
| Flash point: | 168 °C |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Flakes or Crystalline Powder |
| color | White |
| Water Solubility | Insoluble |
| Merck | 14,7278 |
| BRN | 1074863 |
| Stability: | Stable. Incompatible with strong oxidizing agents. Flammable. |
| CAS DataBase Reference | 102-09-0(CAS DataBase Reference) |
| NIST Chemistry Reference | Diphenyl carbonate(102-09-0) |
| EPA Substance Registry System | Carbonic acid, diphenyl ester (102-09-0) |
Safety information for Diphenyl carbonate
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07  Environment GHS09 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H410:Hazardous to the aquatic environment, long-term hazard |
| Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P273:Avoid release to the environment. P391:Collect spillage. Hazardous to the aquatic environment P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P501:Dispose of contents/container to..… |
Computed Descriptors for Diphenyl carbonate
| InChIKey | ROORDVPLFPIABK-UHFFFAOYSA-N |
Diphenyl carbonate manufacturer
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product: 102-09-0 Diphenyl carbonate 98%
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