DIMETHYLSILYLDIETHYLAMINE
- CAS NO.：13686-66-3
- Empirical Formula: C6H17NSi
- Molecular Weight: 131.29
- MDL number: MFCD00048523
- EINECS: 237-202-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-07-12 16:46:28
What is DIMETHYLSILYLDIETHYLAMINE?
Physical properties
bp 112°C/760 mmHg; n20 D 1.4087; d20 4 0.7505 g cm?3.
The Uses of DIMETHYLSILYLDIETHYLAMINE
N,N-Diethylaminodimethylsilane is a
useful reagent for the conversion of hydroxy groups of allyl
or homoallyl alcohols into hydrodimethylsilyl ethers for use in
intramolecular hydrosilation reactions. In some cases, N,N-diethylaminodimethylsilane
gives superior results compared to the
more commonly employed 1,1,3,3-tetramethyldisilazane (eq 1).
What are the applications of Application
N,N-Diethyl-1,1-dimethylsilylamine is a silylating agent.
Preparation
by treatment of commercially available chlorodimethylsilane (ClMe2SiH) and diethylamine in the presence of triethylamine in ether, followed by filtration and distillation.
Properties of DIMETHYLSILYLDIETHYLAMINE
| Boiling point: | 109 °C |
| Density | 0.8 |
| refractive index | 1.4080 |
| Flash point: | <-5°C |
| solubility | sol common aprotic organic solvents. |
| pka | 9.05±0.70(Predicted) |
| Specific Gravity | 0.8 |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| BRN | 741862 |
| EPA Substance Registry System | Silanamine, N,N-diethyl-1,1-dimethyl- (13686-66-3) |
Safety information for DIMETHYLSILYLDIETHYLAMINE
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H225:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for DIMETHYLSILYLDIETHYLAMINE
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