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HomeProduct name list(DHQ)2PYR

(DHQ)2PYR

Synonym(s):Hydroquinine 2,5-diphenyl-4,6-pyrimidinediyl diether

(DHQ)2PYR Structural

What is (DHQ)2PYR?

The Uses of (DHQ)2PYR

(DHQ)2Pyr is a bis-Cinchona alkaloid ligand used in enantioselective synthesis applications. Cinchona alkaloids catalyze many useful processes with high enantioselectivities. Cinchona alkaloids can be used as bases to deprotonate substrates with relatively acidic protons forming a contact ion pair between the resulting anion and protonated amine. This interaction leads to a chiral environment around the anion and permits enantioselective reactions with electrophiles. Amination with diimides at the remote γ-position can be carried out using (DHQ)2Pyr to form a diverse range of highly functionalized amine compounds.

What are the applications of Application

(DHQ)2Pyr is a bis-Cinchona alkaloid ligand used in enantioselective synthesis applications

Properties of (DHQ)2PYR

Melting point: 245-248 °C(lit.)
Density  1.29±0.1 g/cm3(Predicted)
storage temp.  Sealed in dry,Room Temperature
pka 9.50±0.70(Predicted)
optical activity [α]20/D +455°, c = 1.2 in methanol

Safety information for (DHQ)2PYR

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for (DHQ)2PYR

InChIKey SWKRDCRSJPRVNF-CVCJRGCISA-N

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