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HomeProduct name listCHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&

CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&

Synonym(s):Dicarbonylchloro[(1,2,3,4,5,-η)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium

CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& Structural

What is CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&?

The Uses of CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&

Reactant for:

  • Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst
  • Ligand exchange
  • Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds

Catalyst for:
  • (S)-Selective dynamic kinetic resolution of secondary alcohols
  • Stereoselective synthesis of neonicorinoide pesticide derivatives
  • Divergent asymmetric synthesis of 3,5-disubstituted piperidines

Properties of CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&

Melting point: 152-167 °C
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C

Safety information for CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&

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