Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Synonym(s):Pentamethylcyclopentadienylrhodium(III) chloride dimer;Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium;1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex;Bis(dichloro(pentamethylcyclopentadienyl)rhodium);Bis(pentamethylcyclopentadienylrhodium dichloride)

CAS NO.：12354-85-7
Empirical Formula: C20H30Cl4Rh210*
Molecular Weight: 618.08
MDL number: MFCD00061552
SAFETY DATA SHEET (SDS)
Update Date: 2024-08-05 20:55:42

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Structural

What is Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]?

Chemical properties

burgundy solid

The Uses of Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A

The Uses of Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

Properties of Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Melting point:	>300°C
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	Chloroform (Sparingly), Methanol (Slightly)
form	crystal
color	red
Water Solubility	Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Stability:	Hygroscopic
NIST Chemistry Reference	Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)

Safety information for Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.