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HomeProduct name listBis(acetonitrile)dichloropalladium(II)

Bis(acetonitrile)dichloropalladium(II)

Synonym(s):Palladium(II) chloride diacetonitrile complex

  • CAS NO.:14592-56-4
  • Empirical Formula: C4H6Cl2N2Pd
  • Molecular Weight: 259.43
  • MDL number: MFCD00013122
  • EINECS: 238-637-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-04-26 17:21:34
Bis(acetonitrile)dichloropalladium(II) Structural

What is Bis(acetonitrile)dichloropalladium(II)?

Chemical properties

Light yellow to Brown powder to crystaline.

Physical properties

Bis(acetonitrile)dichloropalladium(II) is a yellow-brown solid that is soluble in organic solvents. It is a reagent and a catalyst for reactions that require soluble Pd(II).The compound is similar to bis(benzonitrile)palladium dichloride. 

The Uses of Bis(acetonitrile)dichloropalladium(II)

suzuki reaction

The Uses of Bis(acetonitrile)dichloropalladium(II)

It is used as a catalyst in an ether-directed aza-Claisen rearrangement. Also used in cyclization and cross-coupling reactions. It is applied for olefin isomerization, preparation of acetals and hemiacetal esters.

The Uses of Bis(acetonitrile)dichloropalladium(II)

Catalyst used in an ether-directed aza-Claisen rearrangement.

What are the applications of Application

Bis(acetonitrile)dichloropalladium(II) is a catalyst that is used in ether-directed aza-Claisen rearrangement

What are the applications of Application

Synthesis of Oxindoles
Synthesis of Oxindoles.gif
To a dried screw-cap vial is added anilide (0.3 mmol), AgOCOCF3 (132.5 mg, 0.6 mmol), Bis(acetonitrile)dichloropalladium(II) (3.5 mg, 0.015 mmol) and chlorobenzene. The reaction mixture is stirred at 100-120 °C for 3-12 h in a pre-heated oil bath. After cooling to room temperature, the reaction is diluted with EtOAc and filtered with a glass filter. The filtrate is washed with 5% aqueous NaHCO3 and brine. The extract is dried over MgSO4 and concentrated in vacuo. The crude is purified by preparative TLC.

Preparation

Bis(acetonitrile)palladium dichloride is prepared by reacting two acetonitrile ligands and palladium(II) chloride.

General Description

This product has been enhanced for catalytic efficiency.

Properties of Bis(acetonitrile)dichloropalladium(II)

Melting point: 300 °C
storage temp.  Inert atmosphere,Room Temperature
solubility  Soluble in acetonitrile, acetone, chloroform
form  Fine Crystalline Powder
color  Orange to rust-brown
Water Solubility  insoluble
CAS DataBase Reference 14592-56-4(CAS DataBase Reference)

Safety information for Bis(acetonitrile)dichloropalladium(II)

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.

Computed Descriptors for Bis(acetonitrile)dichloropalladium(II)

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