Bis(acetonitrile)dichloropalladium(II)
Synonym(s):Palladium(II) chloride diacetonitrile complex
- CAS NO.:14592-56-4
- Empirical Formula: C4H6Cl2N2Pd
- Molecular Weight: 259.43
- MDL number: MFCD00013122
- EINECS: 238-637-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-04-26 17:21:34
What is Bis(acetonitrile)dichloropalladium(II)?
Chemical properties
Light yellow to Brown powder to crystaline.
Physical properties
Bis(acetonitrile)dichloropalladium(II) is a yellow-brown solid that is soluble in organic solvents. It is a reagent and a catalyst for reactions that require soluble Pd(II).The compound is similar to bis(benzonitrile)palladium dichloride.
The Uses of Bis(acetonitrile)dichloropalladium(II)
suzuki reaction
The Uses of Bis(acetonitrile)dichloropalladium(II)
It is used as a catalyst in an ether-directed aza-Claisen rearrangement. Also used in cyclization and cross-coupling reactions. It is applied for olefin isomerization, preparation of acetals and hemiacetal esters.
The Uses of Bis(acetonitrile)dichloropalladium(II)
Catalyst used in an ether-directed aza-Claisen rearrangement.
What are the applications of Application
Bis(acetonitrile)dichloropalladium(II) is a catalyst that is used in ether-directed aza-Claisen rearrangement
What are the applications of Application
Synthesis of Oxindoles
To a dried screw-cap vial is added anilide (0.3 mmol), AgOCOCF3 (132.5 mg, 0.6 mmol), Bis(acetonitrile)dichloropalladium(II)
(3.5 mg, 0.015 mmol) and chlorobenzene. The reaction mixture is stirred
at 100-120 °C for 3-12 h in a pre-heated oil bath. After cooling to
room temperature, the reaction is diluted with EtOAc and filtered with a
glass filter. The filtrate is washed with 5% aqueous NaHCO3 and brine. The extract is dried over MgSO4 and concentrated in vacuo. The crude is purified by preparative TLC.
Preparation
Bis(acetonitrile)palladium dichloride is prepared by reacting two acetonitrile ligands and palladium(II) chloride.
General Description
This product has been enhanced for catalytic efficiency.
Properties of Bis(acetonitrile)dichloropalladium(II)
Melting point: | 300 °C |
storage temp. | Inert atmosphere,Room Temperature |
solubility | Soluble in acetonitrile, acetone, chloroform |
form | Fine Crystalline Powder |
color | Orange to rust-brown |
Water Solubility | insoluble |
CAS DataBase Reference | 14592-56-4(CAS DataBase Reference) |
Safety information for Bis(acetonitrile)dichloropalladium(II)
Signal word | Danger |
Pictogram(s) |
Skull and Crossbones Acute Toxicity GHS06 |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. |
Computed Descriptors for Bis(acetonitrile)dichloropalladium(II)
Abamectin manufacturer
Vineeth Precious Catalysts Pvt Ltd
Metal Chem India
Johnson Matthey Chemicals India Pvt Ltd
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