Acetylacetonatobis(2-phenylpyridine)iridium
Synonym(s):(ppy)2Ir(acac);Bis[2-(2-pyridinyl-N)phenyl-C](acetylacetonato)iridium(III);Ir(ppy)2(acac)
- CAS NO.：337526-85-9
- Empirical Formula: C27H23IrN2O2
- Molecular Weight: 599.711
- MDL number: MFCD12022553
- EINECS: 803-559-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-01-02 16:51:54
What is Acetylacetonatobis(2-phenylpyridine)iridium?
Description
Like?Ir(ppy)3, bis[2-(2-pyridinyl-N)phenyl-C](acetylacetonato)iridium(III), or?Ir(ppy)2(acac), is one of the most studied OLED materials due to its high quantum yields. When doped into 3,5-Diphenyl-4-(1-naphthyl)-1H-1,2,4-triazole (TAZ), very high external quantum efficiencies of (19.06 ± 1.0%) and luminous power efficiencies of 60±5 lm/W were achieved. This was attributed to the nearly 100% internal phosphorescence efficiency of Ir(ppy)2(acac), coupled with balanced hole and electron injection, and triplet exciton confinement within the light-emitting layer.
The Uses of Acetylacetonatobis(2-phenylpyridine)iridium
(ppy)2Ir(acac) used in green phosphorescent OLED devices as dopant/emitter achieved high brightness of 130800 cd m_2 at a current density of 1550 mA cm_2 (13 V), and high quantum efficiency (15~16%).
Properties of Acetylacetonatobis(2-phenylpyridine)iridium
| Melting point: | 349-356°C |
| form | powder |
| color | Light yellow to Yellow to Orange |
| Absorption | λmax?259 in THF |
Safety information for Acetylacetonatobis(2-phenylpyridine)iridium
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Acetylacetonatobis(2-phenylpyridine)iridium
| InChIKey | QISLNNOQKUEVTI-DVACKJPTSA-M |
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