1,3-Bis(N-carbazolyl)benzene

Synonym(s):N,N′-Dicarbazolyl-3,5-benzene;1,3-Di(9H-carbazol-9-yl)benzene;9,9′-(1,3-Phenylene)bis-9H-carbazole;mCP

CAS NO.：550378-78-4
Empirical Formula: C30H20N2
Molecular Weight: 408.49
MDL number: MFCD09836836
SAFETY DATA SHEET (SDS)
Update Date: 2024-06-26 13:15:32

What is 1,3-Bis(N-carbazolyl)benzene?

Description

1,3-Bis(N-carbazolyl)benzene, known as mCP, with a high triplet energy (ET ?= 2.91 eV) and a very deep highest occupied?molecular orbital (HOMO) level, is often used as host materials for efficient blue phosphorescent light-emitting diodes. Kawamura et al. demonstrated that the photoluminescence internal quantum yield of the blue emitter of FIrpic could approach nearly 100% when doped into the wide energy gap host of mCP .

The Uses of 1,3-Bis(N-carbazolyl)benzene

9,9'-(1,3-Phenylene)bis-9H-carbazole uses as a phosphorescent host material

The Uses of 1,3-Bis(N-carbazolyl)benzene

Material for use as a phosphorescent host material

References

[1] JUAN MENTADO-MORALES. A Promising Thermodynamic Study of Hole Transport Materials to Develop Solar Cells: 1,3-Bis(N-carbazolyl)benzene and 1,4-Bis(diphenylamino)benzene.[J]. Molecules, 2022. DOI:10.3390/molecules27020381.
[2] DAE-KYU KIM; Jong H C; Yoo Lim Kim. Organic Light-Emitting Transistors Based on Pentacene and 4,5-Di(9H-carbazol-9-yl)phthalonitrile Doped onto 1,3-Bis(N-carbazolyl)benzene[J]. The Journal of Physical Chemistry C, 2019. DOI:10.1021/acs.jpcc.9b00150.

Properties of 1,3-Bis(N-carbazolyl)benzene

Melting point:	176-178°C
Boiling point:	644.2±51.0 °C(Predicted)
Density	1.21
storage temp.	Sealed in dry,Room Temperature
form	powder to crystal
color	White to Almost white
InChI	InChI=1S/C30H20N2/c1-5-16-27-23(12-1)24-13-2-6-17-28(24)31(27)21-10-9-11-22(20-21)32-29-18-7-3-14-25(29)26-15-4-8-19-30(26)32/h1-20H
Absorption	λmax 292, 338 nm (in THF)

Safety information for 1,3-Bis(N-carbazolyl)benzene

Signal word	Danger
Pictogram(s)	Corrosion Corrosives GHS05 Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water.