5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
- CAS NO.：16456-81-8
- Empirical Formula: C44H28ClFeN4
- Molecular Weight: 704.03
- MDL number: MFCD00012152
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE?
Chemical properties
dark red or purple powder
The Uses of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
Iron(III) meso-tetraphenylporphine chloride is used catalyzing reagent for silylation reactions.
What are the applications of Application
meso-Tetraphenylporphyrin iron(III) chloride complex is a catalyzing reagent for silylation reactions
Purification Methods
Purify it by extraction from a thimble (Soxhlet) with CHCl3. Concentrate the extract to ca 10mL and add ca 80mL of hot MeOH. Dark blue crystals separate on cooling. It can be recrystallised several times from CHCl3/MeOH. Avoid prolonged heating. It is quite soluble in organic solvents but insoluble in pet ether. [Rothemund & Manotti J Am Chem Soc 70 1808 1948, UV: Dorough et al. J Am Chem Soc 73 4315 1951, Beilstein 26 III 1960.]
Properties of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
| Melting point: | 300 °C |
| storage temp. | Inert atmosphere,Room Temperature |
| form | crystal |
| color | purple |
| Water Solubility | Insoluble in water. |
| Stability: | Stable. Incompatible with strong oxidizing agents, strong acids. |
| CAS DataBase Reference | 16456-81-8 |
Safety information for 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
| InChIKey | ZDYSAMCSFRQDMN-XBZZRTMISA-M |
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