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HomeProduct name list5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Structural

What is 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE?

Chemical properties

dark red or purple powder

The Uses of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

Iron(III) meso-tetraphenylporphine chloride is used catalyzing reagent for silylation reactions.

What are the applications of Application

meso-Tetraphenylporphyrin iron(III) chloride complex is a catalyzing reagent for silylation reactions

Purification Methods

Purify it by extraction from a thimble (Soxhlet) with CHCl3. Concentrate the extract to ca 10mL and add ca 80mL of hot MeOH. Dark blue crystals separate on cooling. It can be recrystallised several times from CHCl3/MeOH. Avoid prolonged heating. It is quite soluble in organic solvents but insoluble in pet ether. [Rothemund & Manotti J Am Chem Soc 70 1808 1948, UV: Dorough et al. J Am Chem Soc 73 4315 1951, Beilstein 26 III 1960.]

Properties of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

Melting point: 300 °C
storage temp.  Inert atmosphere,Room Temperature
form  crystal
color  purple
Water Solubility  Insoluble in water.
Stability: Stable. Incompatible with strong oxidizing agents, strong acids.
CAS DataBase Reference 16456-81-8

Safety information for 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

InChIKey ZDYSAMCSFRQDMN-XBZZRTMISA-M

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