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HomeProduct name list5-Bromo-2-hydroxyacetophenone

5-Bromo-2-hydroxyacetophenone

  • CAS NO.:1450-75-5
  • Empirical Formula: C8H7BrO2
  • Molecular Weight: 215.04
  • MDL number: MFCD00191850
  • EINECS: 604-457-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-03 16:17:04
5-Bromo-2-hydroxyacetophenone Structural

What is 5-Bromo-2-hydroxyacetophenone?

Chemical properties

White to pale yellow crystalline powder

The Uses of 5-Bromo-2-hydroxyacetophenone

5?-Bromo-2?-hydroxyacetophenone (5-Bromo-2-hydroxyacetophenone) may be used in ligand in the preparation of tetrahedral metallocene complexes containing vanadium(IV), synthesis of {2?-[1-(5-bromo-2-oxidophenyl) ethylidene] benzohydrazidato (2-)} tris(pyridine) nickel(II)] pyridine solvate, synthesis of N?-[1-(5-bromo-2-hydroxyphenyl)ethylidene]-3,4,5-trihydroxybenzohydrazide dimethyl sulfoxide solvate trihydrate, preparation of 6-bromochromen-4-one.

Preparation

Preparation by Fries rearrangement of 4-bromophenyl acetate with aluminium chloride without solvent between 110° and 160° (84–91%).

Properties of 5-Bromo-2-hydroxyacetophenone

Melting point: 58-61 °C(lit.)
Boiling point: 135-143 °C(Press: 16 Torr)
Density  1.586±0.06 g/cm3(Predicted)
storage temp.  Sealed in dry,Room Temperature
solubility  Soluble in Chloroform
form  Solid
pka 9.59±0.18(Predicted)
color  White to pale yellow

Safety information for 5-Bromo-2-hydroxyacetophenone

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 5-Bromo-2-hydroxyacetophenone

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