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HomeProduct name list4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL

4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL

Synonym(s):6-Nitroveratryl alcohol

  • CAS NO.:1016-58-6
  • Empirical Formula: C9H11NO5
  • Molecular Weight: 213.19
  • MDL number: MFCD00014701
  • EINECS: 213-806-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-06 15:28:16
4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL Structural

What is 4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL?

Chemical properties

white to light yellow crystal powde

The Uses of 4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL

4,5-Dimethoxy-2-nitrobenzyl alcohol, is used as Reagent for the protection of alcohols, etc., as ethers which can be cleaved by photolysis involving intramolecular rearrangement to derivatives of o-nitrosobenzaldehyde, which are readily cleaved by hydrolysis. It is also used as photochemical protecting groups in organic synthesis. It is also used as a pharmaceutical intermediate.

The Uses of 4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL

4,5-Dimethoxy-2-nitrobenzyl alcohol (6-nitroveratryl alcohol) is suitable reagent used in the synthesis of 4,5-dimethoxy-2-nitrobenzyl methacrylate, a photolabile monomer and 2-(4-((4-(4,5-dimethoxy-2-nitrobenzyloxy)phenyl)cyclohexylidene)methyl)phenoxy)-N,N-dimethylethanamine, a caged cyclofen-OH ligand.

It may be used in the synthesis of the following:

  • 1-[[(chlorocarbonyl)oxy]methyl]-4,5-dimethoxy-2-nitrobenzene
  • bis(4,5-dimethoxy-2-nitrophenyl)ethylene glycol, a photolabile protecting group
  • optically-sensitive monomer
  • nitroveratryl (NV) protected α-hydroxyacetic acid (αG) (NV-αG-OH), required in the preparation of nitroveratryl (NV) protected cyanomethyl (CM) ester of α-hydroxyacetic acid (αG) (NV-αG-CM)
  • 4,5-dimethoxy-2-nitrobenzyl p-nitro-phenylcarbonate
  • 6-nitroveratryloxycarbonyl chloride (NVOCCl), a reagent used in the protection of amino function in amino sugars

General Description

4,5-Dimethoxy-2-nitrobenzyl alcohol (6-Nitroveratryl Alcohol) is 2-nitrobenzyl alcohol derivative. It has been reported to be one of the oxidation products of veratryl (3,4-dimethoxybenzyl) alcohol by lignin peroxidase (isolated from Phanerochaete chrysosporium).

Properties of 4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL

Melting point: 145-148 °C (lit.)
Boiling point: 383.9±37.0 °C(Predicted)
Density  1.307±0.06 g/cm3(Predicted)
storage temp.  Keep in dark place,Sealed in dry,Room Temperature
form  powder to crystal
pka 13.59±0.10(Predicted)
color  White to Yellow to Green
Water Solubility  Soluble in water.
Sensitive  Light Sensitive
λmax 400nm(CH3CN)(lit.)
BRN  1880093
CAS DataBase Reference 1016-58-6(CAS DataBase Reference)

Safety information for 4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL

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