4-Hydroxydiphenylamine
- CAS NO.:122-37-2
- Empirical Formula: C12H11NO
- Molecular Weight: 185.22
- MDL number: MFCD00020142
- EINECS: 204-538-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:07:02
What is 4-Hydroxydiphenylamine ?
The Uses of 4-Hydroxydiphenylamine
4-Hydroxydiphenylamine is used as a reactant in the preparation of iron methylisopropylglyoxime dimethylpyridine/dimethylaminopyridine/phenylaminophenol/imidazolidone complexes.
Definition
Gray solid leaflets. Insoluble in water; soluble in alcohol, ether, acetone, chloroform, alkali, and benzene.
Hazard
Irritant.
Safety Profile
Poison by intravenous route.Moderately toxic by ingestion. A severe eye irritant. Seealso AROMATIC AMINES. When heated todecomposition it emits toxic fumes of NOx.
Purification Methods
Crystallise the amine from chlorobenzene/pet ether, pentane (m 72o) or *C6H6/pet ether (m 70o). [Beilstein 13 III 1019, 13 IV 1052.]
Properties of 4-Hydroxydiphenylamine
Melting point: | 67-73°C |
Boiling point: | 190°C |
Density | 1.0936 (rough estimate) |
refractive index | 1.5300 (estimate) |
Flash point: | 209°C |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
form | powder to lump |
pka | 10.46±0.13(Predicted) |
color | Gray, solid leaflets |
BRN | 511942 |
CAS DataBase Reference | 122-37-2(CAS DataBase Reference) |
NIST Chemistry Reference | Phenol, 4-(phenylamino)-(122-37-2) |
EPA Substance Registry System | Phenol, 4-(phenylamino)- (122-37-2) |
Safety information for 4-Hydroxydiphenylamine
Signal word | Warning |
Pictogram(s) |
Corrosion Corrosives GHS05 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H303:Acute toxicity,oral H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 4-Hydroxydiphenylamine
New Products
(S)-3-Aminobutanenitrile hydrochloride 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid 1-Bromo-3,5-Di-Tert-Butylbenzene S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate 4-IODO BENZOIC ACID 3-NITRO-2-METHYL ANILINE 1-(2,4-DICHLOROPHENYL) ETHANAMINE (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
4-(Trifluoromethylthio)phenol
Sodium diphenylamine-4-sulfonate
Phenol Red
2-Aminodiphenylamine
Diphenylamine,sulfuric acid solution
Phenol
3-Aminophenol
Acetaminophen
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