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HomeProduct name list4-Chlorobenzaldehyde

4-Chlorobenzaldehyde

Synonym(s):4-Chlorobenzaldehyde

  • CAS NO.:104-88-1
  • Empirical Formula: C7H5ClO
  • Molecular Weight: 140.57
  • MDL number: MFCD00003379
  • EINECS: 203-247-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-15 16:24:08
4-Chlorobenzaldehyde Structural

What is 4-Chlorobenzaldehyde?

Chemical properties

4-chlorobenzaldehyde appears as colourless to light yellow crystalline powder. Insoluble in water, easily soluble in ethanol, ether, benzene, soluble in water, acetone. Can be volatilized with water vapor. It is the intermediate of fungicide tebuconazole and plant growth regulator uniconazole.

The Uses of 4-Chlorobenzaldehyde

4-Chlorobenzaldehyde is used as an intermediate for the manufacture of dyestuffs, optical brighteners, pharmaceuticals, agricultural chemicals and metal finishing products.

Preparation

4-Chlorobenzaldehyde can be obtained by chlorinated hydrolysis of p-chlorotoluene: add p-chlorotoluene and phosphorus trichloride to the reaction pot, raise the temperature to 155°C under light and pass chlorine. Control the temperature at 160-170℃ and pass chlorine to the calculated amount to obtain the chlorination solution. Add it to concentrated sulfuric acid with stirring, and stir for 5h at room temperature. let it stand and stratify, take the lower layer into ice water to crystallize, and filter it when it is cold to below 5 ℃. The filter cake was washed with ice water to obtain the crude product, distilled under reduced pressure and collected 108-111℃ (3.33kPa) fraction to obtain p-chlorobenzaldehyde.

Properties of 4-Chlorobenzaldehyde

Melting point: 46 °C
Boiling point: 213-214℃
Density  1.196
vapor density  0.6 (vs air)
vapor pressure  8.75 atm ( 21 °C)
refractive index  1.5550 (estimate)
Flash point: 52 °F
storage temp.  Store below +30°C.
solubility  935mg/l
form  Liquid
color  White to pale yellow
Water Solubility  935 mg/L (20 ºC)
Sensitive  Air Sensitive
BRN  385858
Dielectric constant 72(0.0℃)
Stability: Stable, but air and light-sensitive. Incompatible with strong bases, strong reducing agents, strong oxidizing agents.
CAS DataBase Reference 104-88-1(CAS DataBase Reference)
NIST Chemistry Reference Benzaldehyde, 4-chloro-(104-88-1)
EPA Substance Registry System p-Chlorobenzaldehyde (104-88-1)

Safety information for 4-Chlorobenzaldehyde

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Environment
GHS09
GHS Hazard Statements H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H317:Sensitisation, Skin
H319:Serious eye damage/eye irritation
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 4-Chlorobenzaldehyde

InChIKey AVPYQKSLYISFPO-UHFFFAOYSA-N

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