4-Chlorobenzaldehyde
Synonym(s):4-Chlorobenzaldehyde
- CAS NO.:104-88-1
- Empirical Formula: C7H5ClO
- Molecular Weight: 140.57
- MDL number: MFCD00003379
- EINECS: 203-247-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-15 16:24:08
What is 4-Chlorobenzaldehyde?
Chemical properties
4-chlorobenzaldehyde appears as colourless to light yellow crystalline powder. Insoluble in water, easily soluble in ethanol, ether, benzene, soluble in water, acetone. Can be volatilized with water vapor. It is the intermediate of fungicide tebuconazole and plant growth regulator uniconazole.
The Uses of 4-Chlorobenzaldehyde
4-Chlorobenzaldehyde is used as an intermediate for the manufacture of dyestuffs, optical brighteners, pharmaceuticals, agricultural chemicals and metal finishing products.
Preparation
4-Chlorobenzaldehyde can be obtained by chlorinated hydrolysis of p-chlorotoluene: add p-chlorotoluene and phosphorus trichloride to the reaction pot, raise the temperature to 155°C under light and pass chlorine. Control the temperature at 160-170℃ and pass chlorine to the calculated amount to obtain the chlorination solution. Add it to concentrated sulfuric acid with stirring, and stir for 5h at room temperature. let it stand and stratify, take the lower layer into ice water to crystallize, and filter it when it is cold to below 5 ℃. The filter cake was washed with ice water to obtain the crude product, distilled under reduced pressure and collected 108-111℃ (3.33kPa) fraction to obtain p-chlorobenzaldehyde.
Properties of 4-Chlorobenzaldehyde
Melting point: | 46 °C |
Boiling point: | 213-214℃ |
Density | 1.196 |
vapor density | 0.6 (vs air) |
vapor pressure | 8.75 atm ( 21 °C) |
refractive index | 1.5550 (estimate) |
Flash point: | 52 °F |
storage temp. | Store below +30°C. |
solubility | 935mg/l |
form | Liquid |
color | White to pale yellow |
Water Solubility | 935 mg/L (20 ºC) |
Sensitive | Air Sensitive |
BRN | 385858 |
Dielectric constant | 72(0.0℃) |
Stability: | Stable, but air and light-sensitive. Incompatible with strong bases, strong reducing agents, strong oxidizing agents. |
CAS DataBase Reference | 104-88-1(CAS DataBase Reference) |
NIST Chemistry Reference | Benzaldehyde, 4-chloro-(104-88-1) |
EPA Substance Registry System | p-Chlorobenzaldehyde (104-88-1) |
Safety information for 4-Chlorobenzaldehyde
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 Environment GHS09 |
GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H317:Sensitisation, Skin H319:Serious eye damage/eye irritation H411:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 4-Chlorobenzaldehyde
InChIKey | AVPYQKSLYISFPO-UHFFFAOYSA-N |
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