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HomeProduct name list4'-CHLORO-2,2':6',2''-TERPYRIDINE

4'-CHLORO-2,2':6',2''-TERPYRIDINE

  • CAS NO.:128143-89-5
  • Empirical Formula: C15H10ClN3
  • Molecular Weight: 267.71
  • MDL number: MFCD00191930
  • EINECS: 626-940-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-04-12 23:00:59
4'-CHLORO-2,2':6',2''-TERPYRIDINE Structural

What is 4'-CHLORO-2,2':6',2''-TERPYRIDINE?

Chemical properties

brown crystalline powder

The Uses of 4'-CHLORO-2,2':6',2''-TERPYRIDINE

4'-Chloro-2,2':6',2''-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,μ-bishydroxy-functionalized poly(propylene oxide).

What are the applications of Application

4′-Chloro-2,2′:6′,2′′-terpyridine is used to prepare mono- and bis-terpyridines

General Description

4′-Chloro-2,2′:6′,2′′-terpyridine (4′-Cltpy, Cltpy, Cl-terpy) is a tridentate ligand that contains a terpyridine (tpy) site with a Cl site at the 4 -position. It coordinates with various metal ions through these two sites to form different coordination polymers. Crystal structure study shows terpyridine unit of Cltpy adopts a trans, trans conformation. Mol-ecules assemble themselves into stacked columns along the b axis, with an inter-planar distance of 3.51?. It undergoes Williamson type ether reactions with α,ω-bishydroxy-functionalized poly(propylene oxide). It undergoes Williamson type reaction with α-hydroxy-ω-carboxy-functionalized poly(ethylen-oxide) to afford monoterpyridine terminated telechelics.

Properties of 4'-CHLORO-2,2':6',2''-TERPYRIDINE

Melting point: 148-150 °C(lit.)
Boiling point: 416.73°C (rough estimate)
Density  1.2245 (rough estimate)
refractive index  1.6010 (estimate)
storage temp.  Keep in dark place,Sealed in dry,Room Temperature
form  Crystalline Powder
pka 4.22±0.22(Predicted)
color  Brown
Water Solubility  Slightly soluble in water.
λmax 278nm(CH3CN)(lit.)
BRN  3613386

Safety information for 4'-CHLORO-2,2':6',2''-TERPYRIDINE

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H301:Acute toxicity,oral
H315:Skin corrosion/irritation
H318:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.

Computed Descriptors for 4'-CHLORO-2,2':6',2''-TERPYRIDINE

InChIKey AHEMFMCEBIJRMU-UHFFFAOYSA-N

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