4'-CHLORO-2,2':6',2''-TERPYRIDINE
- CAS NO.:128143-89-5
- Empirical Formula: C15H10ClN3
- Molecular Weight: 267.71
- MDL number: MFCD00191930
- EINECS: 626-940-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-04-12 23:00:59
What is 4'-CHLORO-2,2':6',2''-TERPYRIDINE?
Chemical properties
brown crystalline powder
The Uses of 4'-CHLORO-2,2':6',2''-TERPYRIDINE
4'-Chloro-2,2':6',2''-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,μ-bishydroxy-functionalized poly(propylene oxide).
What are the applications of Application
4′-Chloro-2,2′:6′,2′′-terpyridine is used to prepare mono- and bis-terpyridines
General Description
4′-Chloro-2,2′:6′,2′′-terpyridine (4′-Cltpy, Cltpy, Cl-terpy) is a tridentate ligand that contains a terpyridine (tpy) site with a Cl site at the 4 -position. It coordinates with various metal ions through these two sites to form different coordination polymers. Crystal structure study shows terpyridine unit of Cltpy adopts a trans, trans conformation. Mol-ecules assemble themselves into stacked columns along the b axis, with an inter-planar distance of 3.51?. It undergoes Williamson type ether reactions with α,ω-bishydroxy-functionalized poly(propylene oxide). It undergoes Williamson type reaction with α-hydroxy-ω-carboxy-functionalized poly(ethylen-oxide) to afford monoterpyridine terminated telechelics.
Properties of 4'-CHLORO-2,2':6',2''-TERPYRIDINE
Melting point: | 148-150 °C(lit.) |
Boiling point: | 416.73°C (rough estimate) |
Density | 1.2245 (rough estimate) |
refractive index | 1.6010 (estimate) |
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
form | Crystalline Powder |
pka | 4.22±0.22(Predicted) |
color | Brown |
Water Solubility | Slightly soluble in water. |
λmax | 278nm(CH3CN)(lit.) |
BRN | 3613386 |
Safety information for 4'-CHLORO-2,2':6',2''-TERPYRIDINE
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 Skull and Crossbones Acute Toxicity GHS06 |
GHS Hazard Statements |
H301:Acute toxicity,oral H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. |
Computed Descriptors for 4'-CHLORO-2,2':6',2''-TERPYRIDINE
InChIKey | AHEMFMCEBIJRMU-UHFFFAOYSA-N |
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Neochemsys Laboratories Pvt Ltd
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