4-Bromobenzyl bromide
Synonym(s):α,4-Dibromotoluene
- CAS NO.：589-15-1
- Empirical Formula: C7H6Br2
- Molecular Weight: 249.93
- MDL number: MFCD00000179
- EINECS: 209-636-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-12-25 17:47:29
What is 4-Bromobenzyl bromide?
Chemical properties
White solid
The Uses of 4-Bromobenzyl bromide
4-Bromobenzyl bromide is used to prepare a 20-member aminomethyl-substituted biaryl library via sequential N-alkylation of various amines.
The Uses of 4-Bromobenzyl bromide
Identification of aromatic carboxylic acids.
What are the applications of Application
4-Bromobenzyl bromide is a useful biochemical used to prepare various amines
Synthesis Reference(s)
Synthetic Communications, 11, p. 669, 1981 DOI: 10.1080/00397918108063642
Purification Methods
Crystallise the bromide from EtOH. [Beilstein 5 IV 836.] LACHRYMATORY.
Properties of 4-Bromobenzyl bromide
| Melting point: | 62-64 °C(lit.) |
| Boiling point: | 115-124 °C (12 mmHg) |
| Density | 1.8246 (rough estimate) |
| refractive index | 1.6066 (estimate) |
| Flash point: | 115-124°C/12mm |
| storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
| form | Coarse Crystalline Solid or Solid Melt |
| color | White to tan |
| Water Solubility | MAY DECOMPOSE |
| Sensitive | Lachrymatory |
| Merck | 14,1409 |
| BRN | 606498 |
| CAS DataBase Reference | 589-15-1(CAS DataBase Reference) |
| EPA Substance Registry System | Benzene, 1-bromo-4-(bromomethyl)- (589-15-1) |
Safety information for 4-Bromobenzyl bromide
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05  Health Hazard GHS08 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation H334:Sensitisation, respiratory |
| Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P284:Wear respiratory protection. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 4-Bromobenzyl bromide
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