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HomeProduct name list4-aminonaphthalene-1,7-disulfonic acid

4-aminonaphthalene-1,7-disulfonic acid

  • CAS NO.:85-74-5
  • Empirical Formula: C10H9NO6S2
  • Molecular Weight: 303.31
  • MDL number: MFCD00021550
  • EINECS: 201-629-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-11-03 13:55:31
4-aminonaphthalene-1,7-disulfonic acid Structural

What is 4-aminonaphthalene-1,7-disulfonic acid?

Description

1-Aminonaphthalene-4,6-disulfonic acid [85-74-5]. (4-aminonaphthalene-1,7-disulfonic acid), Dahl’s acid II, C10H9NO6S2, Mr 303.3, and its alkali-metal salts are soluble in water; the calcium salt is soluble in aqueous ethanol. Caustic fusion at 180℃ yields 1-amino-6-hydroxynaphthalene-4-sulfonic acid, but at higher temperature 4,7-dihydroxynaphthalene1-sulfonic acid is formed. Sulfonation with 35 % oleum at 80℃ gives 1-aminonaphthalene-2,4,6-trisulfonic acid.

Preparation

Naphthionic acid is sulfonated with 25 % oleum at 20℃ to give a 70 : 30 mixture of 1,4,7- and 1,4,6-trisulfonic acids, which is used as mixed Dahl’s acids.

Properties of 4-aminonaphthalene-1,7-disulfonic acid

Boiling point: 205.8°C (rough estimate)
Density  1.6329 (rough estimate)
refractive index  1.7330 (estimate)
pka -0.84±0.40(Predicted)
EPA Substance Registry System 1,7-Naphthalenedisulfonic acid, 4-amino- (85-74-5)

Safety information for 4-aminonaphthalene-1,7-disulfonic acid

Computed Descriptors for 4-aminonaphthalene-1,7-disulfonic acid

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