4-ACETAMIDO-2,2,6,6-TETRAMETHYL-1-OXOPIPERIDINIUM TETRAFLUOROBORATE,95.0+%(T)
Synonym(s):4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium tetrafluoroborate;Bobbitt′s Salt
- CAS NO.：219543-09-6
- Empirical Formula: C11H21BF4N2O2
- Molecular Weight: 0
- MDL number: MFCD29060212
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:38
What is 4-ACETAMIDO-2,2,6,6-TETRAMETHYL-1-OXOPIPERIDINIUM TETRAFLUOROBORATE,95.0+%(T)?
The Uses of 4-ACETAMIDO-2,2,6,6-TETRAMETHYL-1-OXOPIPERIDINIUM TETRAFLUOROBORATE,95.0+%(T)
Bobbitt′s salt (4-NHAc-TEMPO+ BF4 ?)?can be used as a reagent in:???????
- Oxidation of alcohols to their concomitant aldehyde, ketone or carboxylic acid.??????
- Conversion of aldehydes to hexafluoroisopropyl (HFIP) esters via oxidative esterification.,·????????
- Deprotection of allyl ethers to corresponding aldehydes.
- ?Preparation of α,β-unsaturated ketones by dehydrogenation of perfluoroalkyl ketones.
General Description
Bobbitt′s salt (oxoammonium salt) is a commonly used oxidizing agent in organic synthesis for the preparation of useful chemical intermediates. This reagent is highly stable to both air and moisture.
Properties of 4-ACETAMIDO-2,2,6,6-TETRAMETHYL-1-OXOPIPERIDINIUM TETRAFLUOROBORATE,95.0+%(T)
| Melting point: | 191-197°C (decomposition) |
| storage temp. | 2-8°C |
| solubility | soluble in Methanol |
| form | powder to crystal |
| color | Light yellow to Yellow to Orange |
Safety information for 4-ACETAMIDO-2,2,6,6-TETRAMETHYL-1-OXOPIPERIDINIUM TETRAFLUOROBORATE,95.0+%(T)
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 4-ACETAMIDO-2,2,6,6-TETRAMETHYL-1-OXOPIPERIDINIUM TETRAFLUOROBORATE,95.0+%(T)
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