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HomeProduct name list3-PHENYL-1-PROPYNE

3-PHENYL-1-PROPYNE

3-PHENYL-1-PROPYNE Structural

What is 3-PHENYL-1-PROPYNE?

Chemical properties

Clear colorless to yellow liquid

The Uses of 3-PHENYL-1-PROPYNE

3-Phenyl-1-propyne is used as a starting material in the synthesis of 4-phenyl-2-butyn-1-ol. It is also used in the preparation of beta-hydroxytriazoles and indoles.

Synthesis Reference(s)

The Journal of Organic Chemistry, 47, p. 1837, 1982 DOI: 10.1021/jo00349a007

General Description

3-Phenyl-1-propyne is a 3-aryl-1-propyne. The electronic transition of the resonance-stabilized 1-phenylpropargyl radical, produced in a jet-cooled discharge of 3-phenyl-1-propyne, has been studied by laser-induced fluorescence excitation and dispersed single vibronic level fluorescence (SVLF) spectroscopy. The microwave rotational spectrum of 3-phenyl-1-propyne (propargyl benzene) has been studied and its stable conformation is reported to have coplanar carbon atoms. Reaction of N-methyl-N-phenylhydrazine or N-phenylhydrazine with 3-phenyl-1-propyne is reported to yield indoles. 3-Phenyl-1-propyne is reported to react with styrene oxide and sodium azide, to afford β-hydroxytriazoles.

Properties of 3-PHENYL-1-PROPYNE

Boiling point: 75 °C20 mm Hg(lit.)
Density  0.934 g/mL at 25 °C(lit.)
refractive index  n20/D 1.526(lit.)
Flash point: 126 °F
storage temp.  Flammables area
solubility  Chloroform (Sparingly), DMSO (Slightly)
form  Liquid
Specific Gravity 0.934
color  Clear colorless to yellow
Stability: Volatile
CAS DataBase Reference 10147-11-2

Safety information for 3-PHENYL-1-PROPYNE

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P241:Use explosion-proof electrical/ventilating/lighting/…/equipment.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 3-PHENYL-1-PROPYNE

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