3-METHYL-2-BUTANOL
Synonym(s):3-Methyl-2-butanol;Isopropyl methyl carbinol
- CAS NO.:598-75-4
- Empirical Formula: C5H12O
- Molecular Weight: 88.15
- MDL number: MFCD00004527
- EINECS: 209-950-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-11-23 20:02:38
What is 3-METHYL-2-BUTANOL?
Chemical properties
CLEAR COLOURLESS LIQUID
Chemical properties
Amyl alcohols (pentanols) have eight isomers. All are flammable, colorless liquids, except the isomer 2,2- dimethyl-1-propanol, which is a crystalline solid.
Chemical properties
3-Methyl-2-butanol has a fruity, fresh odor.
The Uses of 3-METHYL-2-BUTANOL
3-Methyl-2-butanol has been used as a reference for microbially produced, volatile organic compounds (MVOC) in GC-MS analyses.
The Uses of 3-METHYL-2-BUTANOL
A flotation agent, a solvent, and in organic synthesis.
Definition
ChEBI: A secondary alcohol that is 2-butanol carrying an additional methyl substituent at position 3.
Hazard
Moderately toxic.
Potential Exposure
(n-isomer); Suspected reprotoxic hazard, Primary irritant (w/o allergic reaction), (iso-, primary): Possible risk of forming tumors, Primary irritant (w/o allergic reaction), (sec-, active primary-, and other isomers) Primary irritant (w/o allergic reaction). Used as a solvent in organic synthesis and synthetic flavoring, pharmaceuticals, corrosion inhibitors; making plastics and other chemicals; as a flotation agent. The (n-isomer) is used in preparation of oil additives, plasticizers, synthetic lubricants, and as a solvent.
Shipping
UN2811 Pentanols, Hazard Class: 3; Labels: 3- Flammable liquid. UN1987 Alcohols, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid.
Purification Methods
Reflux it with magnesium, then fractionally distil it. [Beilstein 1 IV 1675.]
Incompatibilities
Forms an explosive mixture with air. Contact with strong oxidizers and hydrogen trisulfide may cause fire and explosions. Incompatible with strong acids. Violent reaction with alkaline earth metals forming hydrogen, a flammable gas.
Waste Disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
Properties of 3-METHYL-2-BUTANOL
Melting point: | -51.44°C (estimate) |
Boiling point: | 112 °C (lit.) |
Density | 0.818 g/mL at 25 °C (lit.) |
refractive index | n |
FEMA | 3703 | 3-METHYL-2-BUTANOL |
Flash point: | 80 °F |
storage temp. | Flammables area |
solubility | 56g/l |
pka | 15.17±0.20(Predicted) |
form | Liquid |
color | Clear colorless |
Odor | fruity |
explosive limit | 1.2-10.5%(V) |
Water Solubility | Miscible in Ether, Alcohols. Slightly soluble in water. (2.8g/100mL, 30°C) |
Merck | 14,6031 |
JECFA Number | 300 |
BRN | 1718800 |
Exposure limits | NIOSH: IDLH 500 ppm; TWA 100 ppm(360 mg/m3); STEL 125 ppm(450 mg/m3) |
CAS DataBase Reference | 598-75-4(CAS DataBase Reference) |
EPA Substance Registry System | 2-Butanol, 3-methyl- (598-75-4) |
Safety information for 3-METHYL-2-BUTANOL
Signal word | Warning |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H226:Flammable liquids H332:Acute toxicity,inhalation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. |
Computed Descriptors for 3-METHYL-2-BUTANOL
New Products
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