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HomeProduct name list3-METHYL-2-BUTANOL

3-METHYL-2-BUTANOL

Synonym(s):3-Methyl-2-butanol;Isopropyl methyl carbinol

  • CAS NO.:598-75-4
  • Empirical Formula: C5H12O
  • Molecular Weight: 88.15
  • MDL number: MFCD00004527
  • EINECS: 209-950-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-11-23 20:02:38
3-METHYL-2-BUTANOL Structural

What is 3-METHYL-2-BUTANOL?

Chemical properties

CLEAR COLOURLESS LIQUID

Chemical properties

Amyl alcohols (pentanols) have eight isomers. All are flammable, colorless liquids, except the isomer 2,2- dimethyl-1-propanol, which is a crystalline solid.

Chemical properties

3-Methyl-2-butanol has a fruity, fresh odor.

The Uses of 3-METHYL-2-BUTANOL

3-Methyl-2-butanol has been used as a reference for microbially produced, volatile organic compounds (MVOC) in GC-MS analyses.

The Uses of 3-METHYL-2-BUTANOL

A flotation agent, a solvent, and in organic synthesis.

Definition

ChEBI: A secondary alcohol that is 2-butanol carrying an additional methyl substituent at position 3.

Hazard

Moderately toxic.

Potential Exposure

(n-isomer); Suspected reprotoxic hazard, Primary irritant (w/o allergic reaction), (iso-, primary): Possible risk of forming tumors, Primary irritant (w/o allergic reaction), (sec-, active primary-, and other isomers) Primary irritant (w/o allergic reaction). Used as a solvent in organic synthesis and synthetic flavoring, pharmaceuticals, corrosion inhibitors; making plastics and other chemicals; as a flotation agent. The (n-isomer) is used in preparation of oil additives, plasticizers, synthetic lubricants, and as a solvent.

Shipping

UN2811 Pentanols, Hazard Class: 3; Labels: 3- Flammable liquid. UN1987 Alcohols, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid.

Purification Methods

Reflux it with magnesium, then fractionally distil it. [Beilstein 1 IV 1675.]

Incompatibilities

Forms an explosive mixture with air. Contact with strong oxidizers and hydrogen trisulfide may cause fire and explosions. Incompatible with strong acids. Violent reaction with alkaline earth metals forming hydrogen, a flammable gas.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Properties of 3-METHYL-2-BUTANOL

Melting point: -51.44°C (estimate)
Boiling point: 112 °C (lit.)
Density  0.818 g/mL at 25 °C (lit.)
refractive index  n20/D 1.409(lit.)
FEMA  3703 | 3-METHYL-2-BUTANOL
Flash point: 80 °F
storage temp.  Flammables area
solubility  56g/l
pka 15.17±0.20(Predicted)
form  Liquid
color  Clear colorless
Odor fruity
explosive limit 1.2-10.5%(V)
Water Solubility  Miscible in Ether, Alcohols. Slightly soluble in water. (2.8g/100mL, 30°C)
Merck  14,6031
JECFA Number 300
BRN  1718800
Exposure limits NIOSH: IDLH 500 ppm; TWA 100 ppm(360 mg/m3); STEL 125 ppm(450 mg/m3)
CAS DataBase Reference 598-75-4(CAS DataBase Reference)
EPA Substance Registry System 2-Butanol, 3-methyl- (598-75-4)

Safety information for 3-METHYL-2-BUTANOL

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H332:Acute toxicity,inhalation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

Computed Descriptors for 3-METHYL-2-BUTANOL

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