3-Methoxysalicylaldehyde
Synonym(s):2-Hydroxy-m-anisaldehyde;2-Hydroxy-3-methoxybenzaldehyde;3-Methoxysalicylaldehyde
- CAS NO.:148-53-8
- Empirical Formula: C8H8O3
- Molecular Weight: 152.15
- MDL number: MFCD00003322
- EINECS: 205-715-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-19 23:02:33
What is 3-Methoxysalicylaldehyde?
Chemical properties
Pale yellow to brown low melting solid
The Uses of 3-Methoxysalicylaldehyde
A positional isomer of Vanillin. o-Vanillin is a more potent antioxidant than Vanillin.
The Uses of 3-Methoxysalicylaldehyde
o-Vanillin has been used to study the solvent-free reaction between o-vanillin and p-toluidine using NMR, DSC and XRD analysis. It was used in the synthesis of new ligand for Fe(III) and Al(lII). It is also used in the study of mutagenesis and as a synthetic precursor for pharmaceuticals.
The Uses of 3-Methoxysalicylaldehyde
o-Vanillin has been used to study the solvent-free reaction between o-vanillin and p-toluidine using NMR, DSC and XRD analysis. It was used in the synthesis of new ligand for Fe(III) and Al(lII).
Definition
ChEBI: A member of the class of benzaldehydes that is salicylaldehyde substituted by a methoxy group at position 3.
Hazard
ortho-Vanillin is harmful if ingested, irritating to eyes, skin and respiratory system, but has an unmistakable high LD50 of 1330 mg/kg in mice.
Biochem/physiol Actions
o-Vanillin induces DNA damage as detected by comet assay.
Properties of 3-Methoxysalicylaldehyde
Melting point: | 40-42 °C (lit.) |
Boiling point: | 265-266 °C (lit.) |
Density | 1.2143 (rough estimate) |
refractive index | 1.4945 (estimate) |
Flash point: | >230 °F |
storage temp. | Store below +30°C. |
solubility | Chloroform (Sparingly), Methanol (Slightly) |
pka | pK1:7.912 (25°C) |
form | Low Melting Solid |
color | Pale yellow to brown |
Water Solubility | slightly soluble |
Sensitive | Air Sensitive |
BRN | 471913 |
Stability: | Hygroscopic |
CAS DataBase Reference | 148-53-8(CAS DataBase Reference) |
NIST Chemistry Reference | Benzaldehyde, 2-hydroxy-3-methoxy-(148-53-8) |
EPA Substance Registry System | Benzaldehyde, 2-hydroxy-3-methoxy- (148-53-8) |
Safety information for 3-Methoxysalicylaldehyde
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for 3-Methoxysalicylaldehyde
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